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Regulation on the protection of groundwater

Original Language Title: Verordnung zum Schutz des Grundwassers

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Regulation on the protection of groundwater (groundwater regulation-GrwV)

Unofficial table of contents

GrwV

Date of completion: 09.11.2010

Full quote:

" Groundwater regulation of 9 November 2010 (BGBl. I p. 1513) "

*)
This Regulation shall be used for the implementation of
-
Directive 2000 /60/EC of the European Parliament and of the Council of 23 1 October 2000 establishing a framework for Community action in the field of water policy (OJ C 327, 28.11.2000, p. 1), which was last amended by Directive 2009 /31/EC (OJ L 327, 22.12.2009, p. OJ L 140, 5.6.2009, p.114),
-
Directive 2006 /118/EC of the European Parliament and of the Council of 12 December 2006 on the protection of groundwater against pollution and deterioration (OJ L 327, 30.12.2006, p. OJ L 372, 27.12.2006, p. 19, L 53, 22.2.2007, p. 30, L 139, 31.5.2007, p. 39),
-
Commission Directive 2009 /90/EC of 31 July 2009 laying down technical specifications for the chemical analysis and monitoring of the state of water status in accordance with Directive 2000 /60/EC of the European Parliament and of the Council (OJ L 327, 22.12.2009, p. OJ L 201, 1.8.2009, p. 36).

Footnote

(+ + + Text proof: 16.11.2010 + + +) 
(+ + + Official note from the norm-provider on EC law:
Implementation of the
ERL 60/2000 (CELEX Nr: 32000L0060)
ERL 118/2006 (CELEX Nr: 32006L0118)
ERL 90/2009 (CELEX Nr: 32009L0090) + + +)

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Input formula

Pursuant to Article 23 (1) (1) to (3) and (8) to (12) of the Water Resources Act, paragraph 1, as amended by Article 12 (0a) of the Law of 11 August 2010 (BGBl. 1163), the Federal Government, after consulting the parties concerned, prescries: Unofficial table of contents

Content Summary

§ 1 Definitions
§ 2 Determination and description of groundwater bodies
§ 3 Vulnerable groundwater bodies
§ 4 Classification of the quantitative groundwater status
§ 5 Criteria for the assessment of the chemical groundwater status
§ 6 Determination of the chemical groundwater status
§ 7 Classification of groundwater chemical status
§ 8 Determination of groundwater bodies with less stringent targets
§ 9 Monitoring of the quantitative and chemical groundwater status
§ 10 Rising trend of pollutant concentrations, trend reversal
§ 11 Additional Trending
§ 12 Presentation of the groundwater status and trends
§ 13 Measures to prevent or limit pollutant emissions into groundwater
§ 14 Economic analysis of water use
§ 15 Entry into force, external force
Appendix 1 Description of the groundwater bodies
Appendix 2 Thresholds
Appendix 3 Monitoring of the quantitative groundwater status
Appendix 4 Monitoring of the chemical groundwater status and pollutant trends
Appendix 5 Requirements for analytical methods, laboratories and assessment of monitoring results
Appendix 6 Determination of rising trends, determination of trend reversal
Appendix 7 List of hazardous pollutants and pollutant groups
Appendix 8 List of other pollutants and pollutant groups
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§ 1 Definitions

For the purposes of this Regulation, the following definitions shall apply:
1.
-the concentration of a pollutant, a pollutant group or the value of an indicator of pollution in groundwater, which are laid down for the protection of human health and the environment;
2.
background value of the concentration value of a substance or the value of a pollution indicator which is not or only insignificantly influenced by human activity in a body of groundwater;
3.
significant and sustained upward trend of any statistically significant, ecologically significant and human-related increase in the concentration of a pollutant or group of pollutants, or a negative change a pollution indicator in the ground water;
4.
Entry for water use pursuant to Section 9 (1) (4) and (2) (2) of the Water Resources Act.
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§ 2 Determination and description of the groundwater bodies

(1) On 22 December 2013 and every six years thereafter, the competent authority shall review and update:
1.
the definition of the location and limits of the bodies of groundwater within the meaning of § 3 (6) of the Water Resources Act, in particular taking into account data on hydrology, hydrogeology, geology and land use, and
2.
the description of the bodies of groundwater in accordance with the conditions laid down in Annex 1, point 1.
(2) The description referred to in paragraph 1 (2) shall specify the uses to which the groundwater bodies are subject and how high the risk is that these uses shall determine the uses of the groundwater bodies in accordance with Article 47 of the German Water Resources Act (Wasserbudgets Act). (3) In the case of a body of groundwater which extends beyond the borders of the Federal Republic of Germany to the territory of one or more Member States of the European Union, the Information on the relevant human activities and their impact on the the nature of the groundwater to be determined and retained in accordance with the provisions of Annex 1, point 3, to the extent that this is important for the assessment of the body of groundwater. Unofficial table of contents

§ 3 Dangerous Groundwater Bodies

(1) Groundwater Bodies, which are at risk of not achieving the management objectives in accordance with Article 47 of the Water Resources Act, shall be classified as endangered by the competent authority. Such a risk shall be considered in particular where it is to be expected that the thresholds set out in Annex 2 or those set out in the second sentence of Article 5 (1) or (2) shall be exceeded or that the average annual (2) For vulnerable groundwater bodies referred to in paragraph 1, a further description shall be made by the competent authority in accordance with Annex 1 (2) and (3), in order to determine the extent of the risk, that they do not reach the management goals, to be able to assess more precisely, and to identify which measures are to be included in the programme of measures in accordance with Article 82 of the Water Resources Act. (3) On 22 December 2013 and every six years thereafter, the competent authority shall review and update the detailed description referred to in paragraph 2. 2. Unofficial table of contents

§ 4 Classification of the quantitative groundwater status

(1) The competent authority shall classify the quantity of groundwater as good or bad. (2) The quantitative groundwater status shall be good if:
1.
the development of groundwater levels or swellings shows that the long-term average annual groundwater abstracting does not exceed the usable groundwater supply; and
2.
Changes in groundwater due to human activities will not lead to a situation in which the
a)
the management objectives are missed in accordance with § § 27 and 44 of the Water Resources Act for the surface water bodies in hydraulic connection with the groundwater body,
b)
the condition of these surface waters is significantly deteriorated within the meaning of Section 3 (8) of the Water Resources Act,
c)
Land ecosystems, which are directly dependent on the groundwater body, are significantly damaged and
d)
the groundwater is adversely affected by the inflow of salt water or other harmful substances as a result of spatially and temporally limited changes in the flow direction of the groundwater.
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§ 5 Criteria for the assessment of the chemical groundwater status

(1) The basis for the assessment of the chemical groundwater status shall be the threshold values set out in Appendix 2. Where a pollutant or group of pollutants not listed in Appendix 2 is at risk of failure to meet the management objectives in accordance with Article 47 of the Water Resources Act, the competent authority shall set a threshold value after: The provisions of Part A of Annex II to Directive 2006 /118/EC of the European Parliament and of the Council of 12 December 2006 on the protection of groundwater against pollution and deterioration (OJ L 327, 22.12.2006, p. 19, L 53, 22.2.2007, p. 30, L 139, 31.05.2007, p. 39). (2) The threshold value for a pollutant or group of pollutants, as set out in Annex 2, is lower than the corresponding background value in the Groundwater bodies, the competent authority shall establish a different threshold, taking into account the background value for this groundwater body. The background value is the ninetest percentile of the distribution of the concentrations of substances in the groundwater of the hydrogeological unit relevant to the groundwater body. (3) In the case of bodies of groundwater, which are also located on the territory of another or a number of other Member States of the European Union, the competent authority shall, when setting the thresholds, shall agree with the competent authorities of the neighbouring countries. If the neighbouring state does not belong to the European Union, the competent authority shall endeavour to coordinate the values for the transboundary bodies of groundwater. (4) The competent authority shall enter into the management plan in accordance with § 83 of the Water budget law a summary of the following information:
1.
the number and size of groundwater bodies classified as vulnerable,
2.
pollutants, pollutant groups and pollution indicators, which have led to this classification;
3.
parameters and concentration of the threshold values, as well as the background values in the endangered groundwater body,
4.
Procedures for the discharge of the thresholds, including information on toxicology, ecotoxicology, persistence, bioaccumulation potential and dispersion tendency, and
5.
Interactions between the endangered groundwater bodies, the associated surface waters and the dependent terrestrial ecosystems.
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§ 6 Determination of the chemical groundwater status

(1) The competent authority shall identify and assess the groundwater chemical status on the basis of groundwater investigations and an appropriate conceptual model for the groundwater body. If threshold values are exceeded in the body of groundwater, the following shall be determined and assessed where relevant to the assessment:
1.
the quantities and concentrations of pollutants or groups of pollutants registered by the body of groundwater in the surface water or in directly dependent land ecosystems,
2.
the expected impact on the entries referred to in paragraph 1;
3.
the horizontal and vertical extension of a possible salt entry or of pollutant entries into the groundwater body; and
4.
the risk of the quality of the water taken from the groundwater body and intended for human consumption by pollutants or groups of harmful substances in groundwater.
(2) The competent authority shall, in the event of exceedances of threshold values in groundwater bodies, determine the extensive extent of the burden on each relevant substance or group of substances. The area shares in the groundwater body are determined with the aid of geostatistical or comparable methods. (3) For the classification of the chemical groundwater status in accordance with § 7 (2) and (3), the assessment of the chemical status of the groundwater body is determined by the chemical and chemical substances. The following test results shall be based on the state of groundwater:
1.
the results of the description of the groundwater body in accordance with § 2 (1) and (2) and § 3 (2),
2.
the results of the monitoring of the chemical groundwater status in accordance with Article 9 (2),
3.
the comparison of the annual arithmetic mean of the concentrations of pollutants or groups of pollutants relevant to the hazard of the body of groundwater in accordance with Article 3 (1) at each measuring point in accordance with Article 9 (1) with the threshold values,
4.
the results of the spatial spread of the exceedances of threshold values to be determined in accordance with paragraph 2.
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§ 7 Classification of the chemical groundwater status

(1) The competent authority shall classify the groundwater chemical status as good or bad. (2) The groundwater chemical status shall be good if:
1.
the threshold values set out in Appendix 2 or defined in accordance with Article 5 (1), second sentence or paragraph 2, are not exceeded at any measuring point pursuant to § 9 (1) of the groundwater body;
2.
shall be determined by the monitoring in accordance with § 9 that:
a)
there are no signs of damage to human activities, and changes in electrical conductivity in the case of salts alone do not give sufficient indication of such entries,
b)
the groundwater quality does not lead to a significant deterioration of the ecological or chemical status of the surface water and, accordingly, does not result in a lack of the management objectives in the groundwater in the hydraulic connection of stagnant surface waters, and
c)
the groundwater quality does not lead to significant damage directly from the groundwater body of dependent terrestrial ecosystems.
(3) If a threshold value is exceeded at measuring points in accordance with Article 9 (1), the chemical groundwater status may still be considered to be good if:
1.
one of the following area-related requirements is met:
a)
the total area determined in accordance with Article 6 (2) shall be less than one third of the surface area of the body of groundwater;
b)
in the case of bodies of groundwater greater than 75 square kilometres, the area determined in accordance with point (a) shall be greater than one third of the surface area of the body of groundwater, but shall not exceed 25 square kilometres; or
c)
in the event of adverse changes in groundwater caused by harmful soil changes and contaminated sites, the increase in exceedances to be observed or expected in the foreseeable future to a total of less than 25 square kilometres per year shall be groundwater bodies and, in the case of bodies of groundwater, which are less than 250 square kilometres, limited to less than one-tenth of the surface area of the groundwater body,
2.
the water obtained in the catchment area of a drinking water recovery plant with a water abstraction of more than 100 cubic metres per day, taking into account the processing procedure used, does not exceed the limit value of the water used for the treatment of water, Drinking water regulation, and
3.
the potential uses of groundwater are not significantly affected.
Measuring points where the exceeding of a threshold is due to natural causes not caused by human activities shall be treated as measuring points at which the thresholds are complied with. (4) In accordance with paragraph 3, groundwater bodies are classified in good chemical status, the competent authority shall, in the sub-areas affected by the exceedances of the threshold values, arrange for the necessary measures to be taken in accordance with Article 82 of the Water Resources Act. measures where this is necessary for the protection of aquatic ecosystems, land ecosystems or (5) The competent authority shall publish a summary of the classification of the chemical groundwater status at the level of the river basin districts in the management plan according to § 83 of the Water Resources Act. The summary also provides a description of how threshold values have been taken into account in the classification. Unofficial table of contents

§ 8 Determination of groundwater bodies with less stringent targets

(1) On 22 December 2013 and every six years thereafter, the competent authority shall review and update the determination of the bodies of groundwater for which less stringent targets are set in accordance with Article 47 (3), second sentence, in conjunction with Section 30 of the Water Resources Act. on the market. The determination shall also be carried out on the basis of an assessment of the effects of the quantitative groundwater status
1.
surface waters and associated land ecosystems,
2.
water regulation, flood protection and the dry laying of land,
3.
new sustainable development activities.
(2) On 22 December 2013 and every six years thereafter, the competent authority shall also review and update the determination of the groundwater bodies for which the best possible use of the groundwater body in accordance with Article 47 (3) sentence 2 in conjunction with Section 30 of the Water Resources Act chemical status, because the groundwater bodies are so polluted as a result of the effects of human activity that a good groundwater chemical status would not be achieved, or could only be achieved with disproportionately high costs. Unofficial table of contents

§ 9 Monitoring of the quantitative and chemical groundwater status

(1) In each body of groundwater, measuring points shall be established for representative monitoring of the quantitative groundwater status in accordance with Appendix 3 and the chemical groundwater status in accordance with Annex 4, point 1, and to (2) On the basis of the description of the bodies of groundwater in accordance with Appendix 1 and the assessment of the risk in accordance with § 2 (2), a programme for the period of validity of the management plan in accordance with Section 83 of the Water Resources Act shall be: Monitoring of the chemical groundwater status of all groundwater bodies in accordance with the Annex 4, point 2. If, according to the results of the monitoring, the management objectives are not reached in accordance with § 47 of the German Water Resources Act or groundwater bodies are classified as endangered in accordance with § 3, paragraph 1, between the time periods of the Monitoring of the chemical groundwater status in accordance with Annex 4, point 3. (3) The tests shall be carried out in accordance with the control and analysis methods according to Appendix 5. Unofficial table of contents

§ 10 Rising trend of pollutant concentrations, trend reversal

(1) On the basis of the monitoring and operational supervision referred to in Article 9 (2), the competent authority shall determine, for each body of groundwater that has been classified as endangered in accordance with Section 3 (1), any significant and sustained the increasing trend in the body of groundwater in accordance with Annex 6. (2) is a trend according to Annex 6, point 1, which is likely to pose a significant risk to the quality of the aquatic or terrestrial ecosystems, to human health or to the potential or potential of the environment. the real legitimate uses of the waters, the competent authority responsible for Authority to take the necessary measures to reverse the trend. Measures for trend reversal shall be required if the concentration of pollutants reaches three quarters of the threshold set in accordance with Article 5 (1). The competent authority shall establish earlier starting concentrations for trend reversal measures where this is necessary for reasons of protection of drinking water supply or water or land ecosystems. It determines a higher initial concentration for measures of trend reversal if:
1.
the limit of destination for certain pollutants does not allow an initial concentration of three quarters of the threshold value to be fixed in accordance with Appendix 2, or
2.
Thresholds according to § 5 (2) have been established.
(3) Within the duration of a management plan according to § 83 of the Water Resources Act, the initial concentration for measures of trend reversal shall not be changed. (4) Trending shall be determined taking into account the findings of the investigation of the first management plan referred to in Article 83 of the Water Resources Act and shall be repeated at least once every six years. (5) The studies shall be carried out in accordance with the methods of control and analysis of Appendix 5. (6) Management Plan 2015 and thereafter every six years is about the nature of the Report on the trend and explain the reasons for setting the trend reversal points. Unofficial table of contents

Section 11 Additional Trending

(1) In the case of bodies of groundwater which have been classified as being threatened on the basis of harmful soil changes or contaminated sites in accordance with Article 3 (1), the competent authority shall, on the basis of appropriate monitoring measures, initiate an additional Determination of whether there is a trend of increasing expansion of pollutants in the groundwater body. If the pollutant entries in the groundwater body caused by the harmful soil changes or contaminated sites expand and this leads to a deterioration of the chemical groundwater status or poses a danger to the human Health, the public water supply or the environment, shall be required to take the necessary measures to prevent further expansion. The soil protection legislation for the remediation of contaminated sites and harmful soil changes shall remain unaffected. (2) The tests shall be carried out in accordance with the control and analytical methods of Appendix 5. (3) The competent authority shall take the necessary measures to ensure that the Results of the Trending investigations in the management plan according to § 83 of the Water Resources Act for the catchment areas together. Unofficial table of contents

§ 12 Presentation of the state of groundwater and trends

(1) The classification of the groundwater status according to § 4 and the chemical groundwater status in accordance with § 7 as well as the trends determined in accordance with § § 10 and 11 shall be presented in maps by the competent authority. Separate cards must be used for the quantitative and chemical groundwater status. (2) A good groundwater status is to be marked with the colour green and a poor groundwater state with the colour red. (3) groundwater bodies, which have a significant and sustained upward trend in pollutant concentrations due to human activity, are to be marked with a black point; a trend reversal shall be indicated by a blue dot. Trend and trend reversal are to be presented on the map for the chemical groundwater state. Unofficial table of contents

Section 13 Measures to prevent or limit pollutant entries into groundwater

(1) In order to achieve the objectives set out in § 47 of the Water Resources Act, measures shall be included in the programmes of measures in accordance with Section 82 of the Water Resources Act, which shall include the entry of the pollutants and pollutant groups referred to in Appendix 7 into the Prevent groundwater. Entries of such pollutants shall not be authorised in the context of the implementation of these programmes of measures. The second sentence shall not apply if the pollutants are introduced into the groundwater in such a small quantity and concentration that an adverse change in the nature of the groundwater is ruled out. The competent authority shall keep an inventory of entries approved in accordance with the third sentence. If entries are permitted, the groundwater concerned must be monitored in accordance with § 9 (2) sentence 2 or in any other appropriate manner. (2) In order to achieve the objectives set out in § 47 of the Water Resources Act, the measures in accordance with § 82 of the Water budget law to include measures to limit the entry of pollutants and pollutant groups in Appendix 8 into groundwater. (3) As far as divergent management objectives according to § 47 (2) sentence 2 and paragraph 3 of the Water Resources Act in the case of the body of groundwater, these shall be used for the purposes of applying paragraphs 1 and 2 of this Article consideration. Unofficial table of contents

Section 14 Economic analysis of water use

(1) By 22 December 2013 and every six years thereafter, the economic analyses of the water use carried out before 16 November 2010 shall be the third indent of Article 5 (1) of Directive 2000 /60/EC of the European Parliament and of the Council of 23 1 October 2000 establishing a framework for Community action in the field of water policy (OJ C 327, 28.11.2000, p. 1), which was last amended by Directive 2009 /31/EC (OJ L 327, 22.12.2009, p. 114) has been amended to review and, where necessary, to update. (2) The economic analysis must include the information required to ensure that:
1.
calculations can be carried out in order to cover the principle of covering the costs of water services in accordance with Article 9 of Directive 2000 /60/EC, taking into account the long-term forecasts for the supply and demand of water in the the river basin district, and
2.
the most cost-effective combinations of measures for the programme of measures can be assessed in relation to the use of water.
(3) In the event of a disproportionate effort, in particular taking into account the cost of collecting the data in question, it may also be possible to estimate the quantity, prices and costs associated with the water services, estimates of the relevant investments, including the corresponding forward planning, and estimates of the potential costs of the measures for the programme of measures. Unofficial table of contents

Section 15 Entry into force, expiry of the external force

This Regulation shall enter into force on the day following the date of delivery. At the same time, the basic water regulation of 18 March 1997 (BGBl. I p. 542). Unofficial table of contents

Final formula

The Federal Council has agreed. Unofficial table of contents

Appendix 1 (to § 2 (1) and (3), § 3 (2))
Description of the groundwater bodies

(Fundstelle: BGBl. I 2010, 1519-1520)
1.
Description The description of the groundwater bodies must contain at least:
1.1
the location and limits of the bodies of groundwater,
1.2
loads to which the groundwater body may be exposed, including
1.2.1
diffuse sources of pollution,
1.2.2
toxic sources of pollutants,
1.2.3
Groundwater detentists,
1.2.4
artificial groundwater rebates,
1.3
a general characteristic of the outer layers above ground water in the catchment area from which the groundwater recharge is carried out,
1.4
Groundwater bodies, from which surface water ecosystems or land ecosystems are directly dependent.
You can use existing data for the description, for example: Hydrological, geological and bogus data, as well as land use, input and retrieval data. For the purpose of this initial description, groundwater bodies can be combined into groups.
2.
Further description The effects of relevant human activities on groundwater are to be described. The following information shall be obtained in so far as they are relevant for the assessment of the body of groundwater or of the group of bodies of groundwater:
2.1
geological characteristics of the aquisite, including the extent and type of geological units;
2.2
hydrogeological characteristics of the aquilot, including porosity, permeability and tension,
2.3
Characteristics of the outer layers and soils of the catchment area from which groundwater reformation occurs, including its thickness, porosity, permeability and adsorption properties;
2.4
Layings in the groundwater of the groundwater body,
2.5
Inventory of surface water and land ecosystems in hydraulic communication with the groundwater body,
2.6
Estimation of the flow direction of the groundwater and the water exchange rates between the groundwater body and the surface waters in hydraulic connection,
2.7
adequate data for the calculation of long-term average annual groundwater retraining,
2.8
Description of the chemical composition of the groundwater, including entries from human activities; in determining the background values for these groundwater bodies, typologies may be used for the description of groundwater .
3.
Description of cross-border or endangered groundwater bodies
In accordance with Article 2 (1) and Article 3 (2), the following information shall be collected and kept for all groundwater bodies which are transboundary or at risk, provided that they are relevant for the assessment of the groundwater bodies:
3.1
Sampling points, from which ten cubic metres and more water are taken from the daily average, and
3.1.1
the location of the withdrawal point,
3.1.2
the average annual amount of the withdrawal;
3.1.3
chemical composition of the extracted water.
3.2
Drinking water abstraction points from which, on average, ten cubic metres of water and more are taken from the drinking water supply, or 50 persons and more are supplied, and
3.2.1
the location of the withdrawal point,
3.2.2
the average annual amount of the withdrawal;
3.2.3
chemical composition of the extracted water.
3.3
Direct discharges of water into the ground water, namely
3.3.1
the location of the point of introduction,
3.3.2
Introduction quantities,
3.3.3
the chemical composition and physical nature of the water instituted.
3.4
Land use of the areas where groundwater retraining is carried out, including the entry of pollutants and the changes caused by human activities with regard to groundwater reformation, such as the derivation of Rainwater and drains of sealed surfaces, artificial enrichment, introduction and drainage.
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Appendix 2 (to § 3 (1), § 5 (1) and (2), § 7 (2) (1), § 10 (2) sentence 4, point 1)
Thresholds

(Fundstelle: BGBl. I 2010, 1521)
1) SubstanceNameCAS-Nr.1 Threshold Termination Criterion
Nitrates (NO3) - ) - 50 mg/l Groundwater quality standard in accordance with Directive 2006 /118/EC
Active substances in plant protection products and biocidal products, including relevant metabolites, degradation and reaction products 2) - 0.1 μg/l each
Total 3) 0.5
Groundwater quality standard in accordance with Directive 2006 /118/EC
Arsenic (As) 7440-38-2 10 µ g/l Drinking water limit for chemical parameters
Cadmium (Cd) 7440-43-9 0.5 µ g/l Ecotoxicologically derived: PNEC + background value
Lead (Pb) 7439-92-1 10 µ g/l Drinking water limit for chemical parameters
Mercury (Hg) 7439-97-6 0.2 µ g/l Ecotoxicologically derived: target for surface water + background value
Ammonium (NH4) + ) 7664-41-7 0.5 mg/l Drinking water limit for indicator parameters
Chloride (Cl) - ) 168876-00-6 250 mg/l Drinking water limit for indicator parameters
Sulphate (SO4) 2- ) 14808-79-8 240 mg/l Drinking water limit for indicator parameters
Total from Tri-and
Tetrachloroethene
79-01-6
127-18-4
10 μg/l Drinking water limit for chemical parameters
1)
Chemical Abstracts Service, International registration number for chemical substances.
2)
According to the Plant Protection Act, as amended by the Notice of 14 May 1998 (BGBl. I p. 971, 1527, 3512), most recently by Article 13 of the Law of 29 July 2009 (BGBl. 2542), and the Biocides Act of 20 July 2002 (BGBl. 2076), which is based on Article 2 (3) (18) of the Law of 1 September 2005 (BGBl. 2618).
3)
All in all, the sum of all individual plant protection products and biocides, which are detected in the monitoring process and which are determined in terms of quantity, is included, including the relevant metabolism, degradation and reaction products.
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Appendix 3 (to § 9 paragraph 1)
Monitoring of the quantitative groundwater status

(Fundstelle: BGBl. I 2010, 1522)
1.
Establishment and operation of a measuring network The measuring network for representative groundwater monitoring shall be set up and operated in such a way that the following can be reliably assessed in terms of space and time:
1.1
the quantitative groundwater status, including the available groundwater resources,
1.2
the effects of groundwater management on the groundwater level in the groundwater body and their effects on land ecosystems directly dependent on the groundwater.
Parameters for quantitative monitoring is the ground water level or the source bed.
2.
Density and monitoring frequency of the measurement network
2.1
The density of the measurement site network and the frequency of measurements must allow the estimation of the groundwater levels of each groundwater body, taking into account short-and long-term fluctuations in groundwater reformation.
2.2
In the case of vulnerable groundwater bodies, a sufficient density of the measurement site network and frequency of measurements shall be ensured in order to assess the effects of water detours and discharges on the groundwater level.
2.3
In the case of bodies of groundwater extending beyond the borders of the Federal Republic of Germany, the density of the network of measurement points and the frequency of measurements shall be sufficient to ensure that the flow direction and rate of the flow across the limit shall be met. To be able to assess groundwater.
3.
Presentation of the measuring network The measurement network for the monitoring of the groundwater quantity shall be presented in the river basin management plan on a suitable scale in one or more maps.
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Appendix 4 (to § 9 (1) and (2))
Monitoring of the chemical groundwater status and pollutant trends

(Fundstelle: BGBl. I 2010, 1523-1524)
1.
Establishment and operation of measuring networks
1.1
In order to monitor the chemical groundwater status, measurement networks are to be set up for monitoring monitoring and, where appropriate, for operational monitoring.
1.2
The measurement networks shall be constructed and operated in such a way as to provide a coherent, comprehensive and representative overview of the chemical groundwater status in each body of groundwater, as well as significant and sustained rising trends of Pollutant concentrations within the meaning of Section 1 (3) and their reversal can be identified. It shall ensure that:
1.2.1
-significant and sustained upward trends are sufficiently reliable, accurate and as early as possible, and the reversal of such trends is sufficiently reliable and accurate,
1.2.2
the time-dependent physical and chemical properties of the groundwater body, including the groundwater flow behaviour, the groundwater reformation rates and the dwell time of seepage and groundwater in the water-saturated and -unsaturated subsoil.
1.3
The measurement networks or other relevant monitoring results shall be suitable for determining whether the water obtained is suitable for groundwater bodies from which more than 100 cubic metres of groundwater per day are taken from the drinking water supply. complies with the requirements of the Drinking Water Ordinance, taking into account the processing methods used in each case.
1.4
The measurement networks shall be presented on a suitable scale in the river basin management plan in one or more maps.
1.5
Calculations or estimates of the reliability and accuracy levels of the results obtained in the context of the monitoring shall be recorded for the preparation of the management plan.
1.6
The monitoring results shall be used for the determination of the groundwater bodies for which operational monitoring is to be carried out.
2.
Oversight monitoring
2.1
The monitoring of the oversight shall be used to:
2.1.1
to supplement and validate procedures to assess the impact of human activities on groundwater; and
2.1.2
Identify trends and assess trends.
2.2
Without prejudice to the requirements laid down in point 1.2, a sufficient number of measuring points shall be selected
2.2.1
for vulnerable groundwater bodies and
2.2.2
for groundwater bodies which extend beyond the borders of the Federal Republic of Germany.
2.3
The following parameters must be measured for all selected groundwater bodies:
2.3.1
Oxygen,
2.3.2
pH,
2.3.3
electrical conductivity,
2.3.4
Nitrates,
2.3.5
Ammonium.
2.4
In addition, the vulnerable groundwater bodies should also be monitored for the parameters that indicate the effects of the loads.
2.5
Groundwater bodies extending beyond the borders of the Federal Republic of Germany shall be monitored in addition to the parameters which are important for the protection of all uses associated with the groundwater flow.
3.
Operational monitoring
3.1
Operational monitoring shall be carried out in order to:
3.1.1
determine the chemical groundwater status of the groundwater bodies at risk; and
3.1.2
Long-term trends caused by human activities.
3.2
The measuring points of the operational monitoring shall be selected in such a way that the data obtained are representative of the groundwater status of the groundwater body.
3.3
The parameters to be examined shall be determined on a case-by-case basis, taking into account the parameters which contribute to the risk to the achievement of the objectives.
3.4
Operational monitoring shall be carried out at intervals sufficient to assess the impact of the loads, but at least once a year.
3.5
The operational supervision must be appropriate to demonstrate the effectiveness of the measures taken to achieve the objectives.
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Annex 5 (to § 9, paragraph 3, § 10, paragraph 5, § 11, paragraph 2)
Requirements for analytical methods, laboratories and assessment of monitoring results

(Fundstelle: BGBl. I 2010, 1525-1526)
1.
The requirements for analytical methods analysis methods for the chemical monitoring of the parameters and thresholds referred to in this Regulation must meet the following criteria:
1.1
The analysis methods, including laboratory, field and online methods, are in accordance with the DIN EN ISO/IEC 17025 standard 1) to be validated and documented.
1.2
The extended measurement uncertainty, using the extension factor k = 2, shall not exceed 50 per cent of the analytical methods; it shall be determined at a concentration in the range of the threshold value to be checked. a non-negative parameter that describes the scatter of those values that are assigned to the metric based on the information used. The measurement uncertainty involves the accuracy of the method and determines the range within which the "true value" of the analysis sample is to be expected with a specific, predetermined probability.
1.3
The limits of determination of the methods of analysis applied must not exceed 30 per cent of the relevant threshold value. The limit of determination is a fixed multiple of the detection limit. It corresponds to the concentration of a substance which can be determined with an acceptable level of accuracy. Quantitative analysis results are only given above the limit of determination. In this case, the detection limit is the measurement signal or the concentration value, from which, at a fixed level of confidence, it can be said that a sample differs from a blank sample which does not contain the analyte to be determined. The limit of determination can be made in accordance with the pre-standard ISO/TS 13530 2) shall be determined and verified.
1.4
If there is no analytical method for a parameter which meets the requirements laid down in points 1.2 and 1.3, the monitoring shall be carried out using the best available technology. If, in such cases, the limit of determination exceeds the threshold value and the substance concentration below the limit of determination, the threshold value shall be deemed to be retained. In the analysis operational via its analysis specification of defined parameters, the parameters defined in requirements laid down in the analysis methods.
2.
Requirements for laboratory laboratories The laboratories, which monitor biological quality components or chemical or chemical-physical quality components, have a quality management system in accordance with the standard DIN EN ISO/IEC 17025 3) , They shall demonstrate the competence to carry out the necessary analyses by:
2.1
Participation in laboratory suitability tests with samples, which are representative of the concentration range studied and which are carried out by organisations which meet the requirements of DIN EN ISO/IEC 17043 4) meet, and
2.2
Analysis of available reference materials, which are representative of the samples to be analysed in terms of concentration and matrix.
3.
Requirements for assessment of monitoring results
3.1
Calculation of the annual average
3.1.1
If the values of physico-chemical or chemical measurements are below the limit of determination in a given sample, the measurement results for the calculation of the annual average shall be replaced by half the value of the limit of determination. Sentence 1 shall not apply to parameters representing the sum of substances. In these cases, results for individual substances lying below the limit of determination are set to zero prior to the sum formation.
3.1.2
Where an annual average calculated in accordance with point 3.1.1 is below the limit of determination, this value shall be referred to as the 'small limit of determination'. The environmental quality standard shall then be deemed to be complied with.
3.2
Compliance with threshold values A threshold value shall be considered to be observed at a measuring point if the arithmetic mean of the concentrations measured over a period of one year at this measuring point is less than or equal to the threshold value.
1)
Issue August 2005, published by Beuth-Verlag GmbH, Berlin, and published by the German Patent Office in Munich in terms of archive security.
2)
Edition Vornorm March 2009, published by Beuth-Verlag GmbH, Berlin, and stored in archives at the German Patent Office in Munich.
3)
Issue August 2005, published by Beuth-Verlag GmbH, Berlin, and published by the German Patent Office in Munich in terms of archive security.
4)
Issue May 2010, published by Beuth-Verlag GmbH, Berlin, and published by the German Patent Office in Munich in terms of archive security.
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Appendix 6 (to § 10 (1))
Determination of rising trends, determination of trend reversal

(Fundstelle: BGBl. I 2010, 1527)
1.
Determination of rising trends
1.1
For a measuring point, the determination of a significant and sustained upward trend within the meaning of Section 1 (3) shall be carried out with the aid of:
1.1.1
a linear regression according to the Gaussian principle of the smallest quadratic deviation to be coupled with an outlier test, or alternatively
1.1.2
a man-kendall trendtests.A trend is significant if the statistical probability is at least 95 percent (significance level α = 0.05). In less than five measurement values, trend analysis is not allowed. In the case of trend consideration, the individual values must always be expected at the individual measuring points. In the case of more than one measured value per year, no annual average values may be formed before the trend consideration for the individual measuring point. Measurements below the limit of determination will be taken with the value of the half determination limit for trend analysis . This does not apply to measures which are sums of a particular group of physico-chemical parameters or chemical measures, including their relevant metabolites, degradation and reaction products. In these cases, the results which are below the limit of determination of the individual substances are set to zero.
1.2
For a body of groundwater or a group of bodies of groundwater, there is a significant and sustained trend within the meaning of Section 1 (3), § 10 (2) and (11) if a trend according to point 1.1 is established at measuring points.
2.
Determination of trend reversal The trend reversal will be determined by the formation of sliding six-year intervals over at least three six-year intervals, i.e. from the first to the sixth year, then from the second to the seventh year, from the third to the seventh year. for the eighth year and so on. For each interval, the slope corresponding to number 1 is determined by means of a linear regression and is entered as a series of time. If there is a trend from a rising trend in a falling or falling into a rising trend (zero crossing), this means a trend reversal.
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Appendix 7 (to § 13 (1))
List of hazardous pollutants and pollutant groups

(Fundstelle: BGBl. I 2010, 1528)
1.
Organohalogenic compounds and substances which may form such compounds in water
2.
Organic phosphorus compounds
3.
Organotin compounds
4.
Substances and preparations, as well as their degradation products, their carcinogenic or mutagenic properties or their steroidogenic, thyroid, reproductive or other functions of endocrine system impairing properties in or through the water ,
5.
Persistent hydrocarbons and persistent and bio-accumulative organic toxic substances
6.
Cyanides
7.
Metals and metal compounds
7.1
Lead
7.2
Cadmium
7.3
Nickel
7.4
Mercury
7.5
Thallium
8.
Arsenic and arsenic compounds
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Appendix 8 (to § 13 (2))
List of other pollutants and pollutant groups

(Fundstelle: BGBl. I 2010, 1529)
Non-exhaustive list of pollutants and pollutant groups within the meaning of § 13 (2):
1.
Metals and metal compounds
1.1
Zinc
1.2
Copper
1.3
Chrome
1.4
Selenium
1.5
Antimony
1.6
Molybdenum
1.7
Barium
1.8
Boron
1.9
Vanadium
1.10
Cobalt
2.
Plant protection products and biocides
3.
Suspended
4.
Substances which contribute to eutrophication (in particular nitrate and phosphates)
5.
Substances which have a lasting effect on the oxygen balance and which can be measured on the basis of parameters such as biological oxygen demand, chemical oxygen demand and so on
6.
fluorides
7.
Ammonium and nitrite
8.
Mineral oils and hydrocarbons