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Regulation on requirements for the recovery and disposal of waste wood

Original Language Title: Verordnung über Anforderungen an die Verwertung und Beseitigung von Altholz

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Regulation on requirements for the recovery and disposal of waste wood (altholzverordnung-altholzV)

Unofficial table of contents

AltholzV

Date of completion: 15.08.2002

Full quote:

" Altholzverordnung of 15 August 2002 (BGBl. 3302), as last amended by Article 5 (26) of the Law of 24 February 2012 (BGBl). 212) has been amended "

Status: Last amended by Art. 5 Abs. 26 G v. 24.2.2012 I 212

For more details, please refer to the menu under Notes

Footnote

(+ + + Text evidence from: 1.3.2003 + + +)
The V was referred to as Article 1 (d). V. 15.8.2002 I 3302, issued by the Federal Government after consultation of the parties concerned, with due respect for the rights of the Bundestag with the consent of the Bundesrat. It occurs gem. Art. 5 of this V mWv 1.3.2003 in force. Unofficial table of contents

§ 1 Scope

(1) This Regulation shall apply to:
1.
the recycling of materials,
2.
energy recovery and
3.
the removal of
(2) This Regulation shall apply to:
1.
Producers and owners of old wood,
2.
operators of installations in which old timber is recovered or disposed of;
3.
Public-law disposal providers, in so far as they exploit or eliminate waste wood and
4.
Third parties, associations and self-governing bodies of the economy, to which according to § 16 (2), § 17 (3) or § 18 (2) of the Circular Economic and Waste Act of 27 September 1994 (BGBl. 2705), as last amended by Article 5 of the Law of 6. October 2011 (BGBl. 1986), obligations for the recovery or disposal of old timber have been transferred.
(3) This Regulation shall not apply to the recycling of waste wood, which is not covered by paragraph 1 in conjunction with § 2 no. 7. This Regulation shall not apply to installations pursuant to Section 5 of the Regulation on small and medium-sized combustion plants. Unofficial table of contents

§ 2 Definitions

For the purposes of this Regulation, the terms
1.
Waste wood: industrial timber and used timber, to the extent that such waste is within the meaning of Section 3 (1) of the Circular Economic Law;
2.
Industrial timber: the remains of wood in the woodworking or wood processing industry, including the remains of the wood-based materials used in the wood-based materials industry, as well as the resulting composite materials with a predominant proportion of wood (more than 50 mass per cent);
3.
Used timber: used products made of solid wood, wood-based materials or of composite materials with a predominant proportion of wood (more than 50% by mass);
4.
Altholzcategory:
a)
AltholzCategory A I :natural or only mechanically processed old wood which, when used, has not been contaminated with any other substances in the form of wood,
b)
Category A II: gluten, coated, coated, lacquered or otherwise treated waste wood without organohalogen compounds in the coating and without wood preservatives,
c)
Altholzcategory A III:Altholz with halogen-organic compounds in the coating without wood preservatives,
d)
Category A IV: Altholz treated with wood prevenants, such as railway sleepers, piping masts, hop poles, parapet, and other sawn timber, which are not assigned to the Altholzcategories A I, A II or A III due to its pollution load , with the exception of PCB-Altholz;
5.
PCB waste wood, which is PCB within the meaning of the PCB/PCT Waste Regulation and which is to be disposed of in accordance with the provisions of the PCB/PCT Waste Regulation, in particular insulating and soundproofing panels, which have been treated with polychlorinated biphenyls;
6.
Wood preservatives: substances used in the processing and processing of wood, with biocidal activity against insects or fungi which destroy wood, as well as wood staining fungi, as well as substances to reduce the flammability of wood;
7.
Recycling of waste wood:
a)
Preparation of old wood for wood chips and wood shavings for the production of wood-based materials,
b)
Extraction of synthesis gas for further chemical use and
c)
Production of activated carbon/industrial wood cabbage;
8.
energy recovery of waste wood: utilisation of waste wood within the meaning of § 3 (23) in conjunction with the procedure R 1 of Appendix 2 of the Circular Economic Law;
9.
Alder wood treatment plant: plant for the material or energetic utilization of waste wood, as well as plants for sorting or other treatment of waste wood, including associated storage, respectively;
10.
Interfering substances: inorganic or organic non-wood substances, in particular soil material, stones, concrete, metal parts, paper, paperboard, textiles, plastics or films which adhere, are attached to or connected to the waste wood, to the extent that these are the Hinder recovery.
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§ 3 Requirements for recovery

(1) In order to ensure the unsafe recycling of waste wood, the requirements of Annex I shall be complied with. In accordance with Annex I, for the recovery operations referred to in column 1, only the categories of altholt referred to in column 2 may be used for recycling in accordance with the specific requirements set out in column 3. Wood chips and wood shavings prepared for the production of wood-based materials shall not exceed the limit values set out in Annex II. These shall be deemed to be complied with if the limit value is not exceeded in the moving average of the last four tests carried out in accordance with Article 6 (2) and no analysis result exceeds the limit value by more than 25 per cent. (2) The Energy recovery of waste wood must be carried out in accordance with the regulations of the Federal Immission Control Act and the legal regulations issued on its basis. (3) In the case of a mixture of old wood of different altholzate categories, direct the requirements for recovery referred to in paragraphs 1 and 2 shall be met by the highest altholt category. For the production of wood-based materials, different alto-wood quotas may only be mixed with one another if the requirements of Annex II are met for each of the quotas. Unofficial table of contents

§ 4 High-value of recovery

The processes for the recycling of old wood are of high quality. The first sentence shall apply in accordance with the methods for the energetic utilization of waste wood. Unofficial table of contents

§ 5 Assignment to Altholzcategories

(1) In order to meet the requirements of § 3, the operator of an altholt treatment plant shall ensure that only the altholt categories approved for this purpose are used for the intended recovery and that the used waste wood is defrayed. of interfering substances and free of PCB-old wood. In order to comply with the requirements set out in the first sentence, the operator of the altholt treatment plant shall carry out the following measures:
1.
As a result of visual inspection and sorting, the waste wood is to be assigned to the altholt categories approved for the intended utilization path. In case of suspicion of tar oil treatment, Altholz is assigned to the Altholzcategory A IV. In the case of the assignment, the range and origin of the altholze according to Annex III must be taken into account as a rule presumption. Classification into a different category of altholts is permitted in exceptional cases of exceptional circumstances. It must be justified and documented in the operating diary.
2.
Interfering substances are to be sorted out.
3.
If Altholz is not clearly assigned to an Altholzcategory, it is to be classified into a higher Altholzcategory.
4.
The staff employed for the assignment must have the necessary expertise. The subject-matter requires an operational familiaration on the basis of a single-work plan.
(2) Sorted-out timber and contaminants, for which the plant is not authorised for further disposal, shall be provided separately immediately and must be disposed of for a permissible disposal. Unofficial table of contents

§ 6 Control of waste wood for wood-based material production

(1) In order to verify compliance with the requirements of § 3 (1) sentence 3 and § 3 (3) and § 5 (1) of the processing of waste wood to wood chips and wood shavings for the production of wood material, the operator of the altholt treatment plant in accordance with paragraphs 2 and 3, carry out self-monitoring and, in accordance with the provisions of paragraphs 6, sentences 1 to 3 and 5, ensure regular external monitoring. (2) The operator of the altholt treatment plant has the wood shavings produced in batches of not more than 500 tonnes test. The samples taken shall be subjected to a colouring test for the detection of tar oils and shall be checked for compliance with the limits set out in Annex II, with the exception of the limit values for mercury and polychlorinated biphenyls. Sampling, examination and storage of the samples shall be carried out in accordance with the procedures described in Annex IV. (3) By way of derogation from the third sentence of paragraph 2, operators of altholt treatment plants may, with the agreement of the competent authority, with sufficient sensitivity according to the state of the art. The Federal Ministry for the Environment, Nature Conservation and Nuclear Safety has announced the appropriate test procedures in the Federal Gazette (Bundesanzeiger). (4) Wood chips or wood shavings may only be used in wood-based material production in the following. if the examination and examination referred to in paragraphs 2 and 3 do not result in tar oils and no exceedings of the limit values set out in Annex II. If the test and examination result in a contamination with tar oils or an exceedances of one of the limit values set out in Annex II, the sampled charge shall be assigned to the Altholzcategory A IV. (5) For the classification of waste wood as hazardous waste the Waste Directory Regulation. The references to the waste key in Annex III can be used as a rule presumption. If a waste wood mixture contains waste wood, which is to be classified as hazardous waste, the entire mixture is to be classified as hazardous waste. (6) Quarterly the operator of the altholt treatment plant has the examination and examination of a waste wood. Allow the batch to be carried out by a competent authority or body designated by the competent authority of the country or by the competent authority of the country. This body shall be provided with records and results for self-monitoring in accordance with paragraphs 2 and 3. Paragraph 2 shall apply to the examination and the investigation, with the proviso that compliance with the limit values for mercury and polychlorinated biphenyls shall also be investigated. In the event of non-compliance with the limit values for mercury and polychlorinated biphenyls, the examination of these parameters in accordance with paragraph 2 may be ordered by the competent authority. The operator of the altholt treatment plant shall ensure that the results are communicated to the operator without delay. Where the test and examination result in a burden of tar oils or an exceedation of the limit values set out in Annex II, it shall immediately inform the competent authority thereof. (7) A post referred to in the first sentence of paragraph 6 shall be notified if: the applicant has the necessary technical expertise, independence, reliability and equipment. The notification shall be made by the competent authority of the country in which the applicant has its registered office and shall be valid throughout the territory of the Federal Republic of Germany; if there is no registered office in the territory of the country, the country in which the activity referred to in paragraph 6 shall apply shall be the competent authority of the country in which the applicant should be given priority. The announcement may be accompanied by a reservation of the revocation, a limit, conditions, conditions and the reservation of conditions. The competent authority may require a nationally active applicant to obtain a valid accreditation for compliance with the requirements of DIN EN ISO/IEC 17025:2005 (to be received by Beuth-Verlag GmbH, 10772 Berlin, Germany). Submitted in the form of an archive with the German National Library in Leipzig), which refers to the parameters and examination procedures in accordance with Annex IV. The procedures referred to in this paragraph may be carried out via a single entity. The examination of the application for the publication of a post must be completed within three months; § 42a (2) sentences 2 to 4 of the Administrative Procedure Law shall apply. (8) Equivalent recognition from another Member State of the The European Union or any other Contracting State of the Agreement on the European Economic Area shall be notified in accordance with the first sentence of paragraph 6. When examining the application for the notification referred to in the first sentence of paragraph 6, proof of national evidence from another Member State of the European Union or of another State Party to the Agreement on the European Economic Area shall be the same, where they show that the applicant fulfils the relevant requirements of paragraph 7, first sentence, or the requirements of the issuing State, which are essentially comparable in accordance with their objectives. Proof of proof shall be submitted to the competent authority prior to the commence of the activity in the original or in copy. A certification of the copy as well as a certified German translation can be requested. Unofficial table of contents

§ 7 Control of Altholz for energy recovery

(1) Insofar as the admissibility of the use of waste wood in a plant approved under the German Federal Immission Control Act is limited to certain categories of altholt, the operator of the altholt treatment plant has the pre-broken old wood in batches not more than 500 tonnes each of which, pursuant to Article 5 (1), second sentence, no. 1, first sentence, for a given utilization path, shall be examined for the proper allocation of the altholzes. The test shall be carried out in accordance with Annex V. (2) The sampled charge may be subsequently used for further energy recovery only if the proportion of althwood of higher altholt categories in total 2 per cent per altholt sample taken from does not exceed. If the examination results in a share of altwood of higher altholt categories of more than 2 percent in each of the altholzsamples taken, § 3 para. 3 shall apply, insofar as not a renewed assignment pursuant to § 5 (1) sentence 2 no. 1 sentence 1 is carried out. Section 6 (5) shall apply accordingly. (3) To the extent that old timber is to be used in plants which do not require approval under the Federal Immission Control Act, the tried-and-tested batch shall not subsequently be allowed to continue to be subject to the following provisions of paragraph 2. energy recovery, if there is no old wood of higher categories. The second sentence of paragraph 2 shall apply. (4) In installations with which the exhaust gas or flames are dried in direct contact, the use of waste wood shall be limited to the Altholzcategory A I. (5) Further requirements shall be laid down in accordance with the The Federal Immission Control Act and the regulations based on it remain unaffected. Unofficial table of contents

§ 8 Marketing of Altholz

Waste wood may only be placed on the market for the purpose of material and energy recovery, in order to supply it to an altholt treatment plant in which the requirements of § § 3, 5 to 7 and 12 are complied with. Unofficial table of contents

Section 9 Elimination of old timber

In accordance with § 1 para. 2, Altholz, which is not used for the disposal of a thermal treatment plant approved for this purpose, has to be supplied for the purpose of disposal. Unofficial table of contents

§ 10 Obligations of producers and owners for the separation of old timber

In accordance with Article 1 (2) of the Regulation, the amount of waste wood produced in quantities of more than 1 cubic metres of bulk volume or 0.3 tonnes per day, as well as PCB waste wood, kyanised or tar oil treated with tar oil, shall be at the point of arrival by origin. and to collect, to collect, to collect, to collect, to collect, to collect, to transport and to store separately according to Annex III or to Altholzcategories as well as separately, to the extent that this is necessary for the fulfilment of the requirements laid down in § § 3, 8 and 9 is required. Unofficial table of contents

Section 11 Note and labelling requirements

(1) Anyone who supplies old wood to an altholt treatment plant has to declare the delivered old wood according to altholzcategory and quantity. For the declaration of the Altholze, the delivery note is to be used in accordance with Annex VI. (2) The operator of an altholt treatment plant may only accept the old timber if a delivery note is issued to him. (3) The paragraphs 1 and 2 shall not apply to the delivery of small quantities of up to 100 kilograms. (4) By way of derogation from paragraphs 1 and 2, the declaration of waste wood may also be carried out with the help of practical evidence, in particular of delivery and weighing scales, if these documents are contain the information required for the declaration. (5) Are the The declaration of the altholze can also be carried out in the field "Frei for endorsements" of the control or transfer order. Paragraph 4 shall apply accordingly. The provisions relating to electronic detection in accordance with the Regulation shall apply. Unofficial table of contents

§ 12 Operating diary

(1) The operator of an altholt treatment plant in need of approval shall, in order to verify the proper implementation of the Altholt collection, carry out an operating diary according to the second sentence of this Regulation. The following information shall be entered immediately in the operating log:
1.
significant deviations from the declaration pursuant to section 11 (1) sentence 1 of the assignment in accordance with § 5 (1) sentence 2 no. 1 sentence 1,
2.
the results of the monitoring and external monitoring in accordance with section 6 (1), including the accompanying documentation of the sampling,
3.
the results of the control of waste wood for energy recovery in accordance with § 7 para. 1,
4.
the delivery notes in accordance with section 11 (1) sentence 2,
5.
the nature, quantity and altholt category of the devalued or removed altholze and, in the case of other disposal, type, quantity, altholt category and whereabout of the altholde delivered,
6.
special events, in particular operational disruptions, which may have an impact on the proper recovery and disposal of waste wood, including possible causes, and
7.
the remedial measures taken, if necessary, on the basis of the results of the tests referred to in Article 5 (1), second sentence, first sentence, first sentence, first sentence, section 6 (1) and section 7 (1), or on the basis of special incidents referred to in point 6.
(2) The operating diary shall be regularly checked by the person responsible for the management and supervision of the holding or of a person appointed by the company. It may be carried out by storing the information referred to in paragraph 1 by means of electronic data processing or in the form of individual sheets, including in different areas of activity or parts of operations, where the information referred to in paragraph 1 is legible in German language with printing, writing machine, ballpoint pen or other writing instrument with permanent writing and the sheets are summarized daily. It is to be created in a document-safe way and to protect against unauthorized access. The operating diary must be accessible at all times and must be presented in clear form. (3) The operator of the altholt treatment plant has the data set in the operating log, beginning with the date of the individual adjustment of the individual data. save for five years or to keep the individual sheets on which the information is entered for a period of five years and, at the request of the competent authority, to provide the information stored in clear or single sheets. (4) Where operating conditions are to be carried out in accordance with other provisions, the (5) The provisions of the Ordinance on Detection, Section 4 of the PCB/PCT Waste Regulation as well as § 5 of the Disposal Specialist's Ordinance on Waste Disposal remain unaffected. Unofficial table of contents

§ 13 Administrative Offences

(1) In the sense of § 69 (1) (8) of the German Circular Economy Act, who intentionally or negligently acts in the sense of the law
1.
, contrary to Article 3 (1), sentence 2, an altholt category,
2.
, contrary to Article 3 (3), sentence 2 of the Altholzcontinggente,
3.
Contrary to the first sentence of Article 5 (1), it does not ensure that only approved altholt categories are used and that waste wood is defrayed by impurities and is free from PCB waste wood,
4.
Contrary to Article 6 (1), self-monitoring is not carried out, is not carried out correctly or completely or does not ensure external monitoring,
5.
, contrary to Article 6 (4), first sentence, it supplies wood shavings or wood shavings for use in the manufacture of wood-based materials,
6.
, contrary to the first sentence of Article 7 (2) or the first sentence of the third sentence of paragraph 3, a tried-and-tested charge of further energy recovery
7.
, contrary to § 8 of Altholz,
8.
Contrary to § 9 of the old wood of a thermal treatment plant, does not supply or
9.
contrary to Article 11 (2) of the Altholz.
(2) In the sense of § 69 (2) (15) of the German Circulatory Economic Law, who intentionally or negligently acts in accordance with the law of the law
1.
, contrary to Article 6 (6), sentence 6, the competent authority shall not inform the competent authority, not properly, in full or in time,
2.
contrary to § 11 (1) sentence 1 of the Altholz, not declared right, not complete or not in good time,
3.
Contrary to § 12 (1) sentence 1, an operating diary does not lead, not properly or incompletely, or
4.
shall not, contrary to § 12 (3), save an indication or not at least five years and keep a single sheet not or not at least five years, or not to submit an indication or a single sheet or not in time.
Unofficial table of contents

Annex I (to § 3 (1))
Process for the recycling of old wood

Source of the original text: BGBl. I 2002, 3306
Column 1Column 2Column 3 Nr.VerwertungsProcedure-Authorized altholzcategoriesSpecial Requirements A IA IIA IIIA IV
1 Preparation of old wood for wood chips and wood chips for the production of wood-based materials Yes Yes (yes) The processing of waste wood from the Altholzcategory A III is only permissible if coatings and coatings have been largely removed by pre-treatment or are removed as part of the preparation process.
2 Extraction of synthesis gas for further chemical use Yes Yes Yes Yes A recovery is only permitted in plants approved for this purpose in accordance with § 4 of the Federal Immission Protection Act.
3 Production of activated carbon/industrial wood charcoal Yes Yes Yes Yes A recovery is only permitted in plants approved for this purpose in accordance with § 4 of the Federal Immission Protection Act.
Unofficial table of contents

Annex II (to § 3 (1))
Limit values for wood chips and wood shavings for the production of wood-based materials

Source of the original text: BGBl. I 2002, 3306
Column 1Column 2 Element/connection concentration (milligrams per kilogram of dry mass)
Arsenic 2
Lead 30
Cadmium 2
Chrome 30
Copper 20
Mercury 0.4
Chlorine 600
Fluorine 100
Pentachlorophenol 3
Polychlorinated biphenyls 5
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Annex III (to section 5 (1))
Assignment of common Altholzsortimente in the event of a rule

Source of the original text: BGBl. I 2002, 3307-3308
Common old olk assortment in the case of the rule case waste key
Wood waste from woodworking and processing Cutting, sections, shavings of natural solid wood A I 03 01 05
Cutting, sections, shavings of wood-based materials and other treated wood (without harmful impurities) A II 03 01 05
Packaging Pallets Pallets made of solid wood, such as B.: European pallets, full-wood industrial pallets A I 15 01 03
Pallets of wood-based materials A II 15 01 03
Other pallets, with composite materials A III 15 01 03
Transport crates, solid wood covers A I 15 01 03
Transport crates made of wood-based materials A II 15 01 03
Fruit, vegetable and ornamentals, as well as similar boxes of solid wood A I 15 01 03
Ammunition boxes A IV 15 01 10 *
Cable drums made of solid wood (production before 1989) A IV 15 01 10 *
Solid wood cable drums (manufacture after 1989) A I 15 01 03
Old timber from the construction sector Building site timents Natural solid wood A I 17 02 01
Wood-based materials, shell-wood, treated solid wood (without harmful impurities) A II 17 02 01
Waste wood from demolition and dismantling Floorboards, floors, boards from the interior of the interior (without harmful impurities) A II 17 02 01
Door leaves and frames of interior doors (without harmful impurities) A II 17 02 01
Profile sheets for the room equipment, ceiling panels, decorative beams, etc. (without harmful impurities) A II 17 02 01
Old timber from the construction sector (continued) Old wood from demolition and demolition (continued) Insulating and soundproofing plates which have been treated with means containing polychlorinated biphenyls Elimination 17 06 03 *
Building panels A II 17 02 01
Structural oil for load bearing parts A IV 17 02 04 *
Timber frame and roof rafters A IV 17 02 04 *
Windows, window poles, external doors A IV 17 02 04 *
Impregnated construction timber from the outdoor area A IV 17 02 04 *
Construction and demolition wood with harmful impurities A IV 17 02 04 *
Impregnated old wood from the outdoor area Rail sleepers A IV 17 02 04 *
Line masts A IV 17 02 04 *
Assortment of gardening and landscaping, impregnated garden furniture A IV 17 02 04 *
Agricultural assortments A IV 17 02 04 *
Furniture Furniture, natural solid wood A I 20 01 38
Furniture, without organohalogen compounds in the coating A II 20 01 38
Furniture, with halogen-organic compounds in the coating A III 20 01 38
Waste wood from the barrier waste (mixed assortment) A III 20 03 07
Waste wood from industrial application (e.g. Industrial floors, cooling towers) A IV 17 02 04 *
Old wood from the water construction A IV 17 02 04 *
Waste wood from scrapped ships and wagons A IV 17 02 04 *
Waste wood from damage cases (e.g. B. Brandholz) A IV 17 02 04 *
Fine fraction from the work-up of Altholz to wood-based materials A IV 19 12 06 *
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Annex IV (to § 6)
Guidelines for the analysis of wood chips and wood shavings for the production of wood-based materials

(Fundstelle: BGBl. I 2002, 3309-3313)
1
Examination of wood chips and wood shavings
1.1
Sampling The sampling referred to in § 6 shall be carried out by persons who have the technical expertise required to carry out the sampling. The samples to be examined can be taken from the ongoing production. From the material flow at least all 10 t can be taken from a single sample of at least 2 l, for example with a vessel with stalk, which is held in the throw-off of the conveyor belt. The sampling shall be documented. The documentation shall include at least the date of sampling, the indication of the sampled batch, and the name and signature of the sampler, with which the sampler shall rest assured of the regularity of the sampling. Sample transport and sample storage shall be carried out in such a way that the chemical, physical and biological properties of the sample material are not affected as far as possible.
1.2
Preparation of the laboratory test The batch to be examined is to be prepared for the analytical tests. For this purpose, the individual samples are combined on a clean, smooth substrate to form a mixed sample and homogenized by repeated reaction. A laboratory sample of 500 g with suitable sample thrusters or by keepers and quarters according to DIN 51701, part 3 (August 1985) can be taken from the mixing sample. The laboratory sample shall be divided after drying. One half of the laboratory sample shall be used as a recovery sample. This shall be marked with the date and the analytical number and shall be kept for at least six months.
1.3
Sample preparation The laboratory sample to be prepared for the analysis shall be air-dry. Moist material must be dried before preparation at a well ventilated place or in a laboratory drying oven (drying temperature at most 40 ° C). The laboratory sample is ground to a particle size of < 2 mm in a suitable mill (crusher or cutting mill), optionally with cooling with liquid nitrogen.
1.4
Implementation of the investigationsFor each examination parameter, at least two parallel determinates shall be carried out.
1.4.1
Determination of the moisture content The moisture content is determined in accordance with DIN 52183 (November 1977 edition). The results shall be expressed in% by weight.
1.4.2
Determination of the chlorine and fluorine content According to DIN 51727 (June 2001 edition), the air-dry, milled altholk samples are oxidatively open. The chloride and fluoride contents in the digestion solution are determined by ion chromatography in accordance with DIN EN ISO 10304, part 1 (April 1995 edition). The results shall be expressed in milligrams per kilogram of dry matter.
1.4.3
Determination of the elements arsenic, lead, cadmium, chromium, copper and mercury The air-dry, ground altholk samples are drawn up in accordance with DIN EN 13657 (draft October 1999) with Königswasser. The measurement of the element concentrations in the digestion solution is carried out according to one of the following methods of investigation:
Element investigation method (s)
Arsenic DIN EN ISO 11969 (November 1996 edition)
Lead DIN 38406, part 6 (July 1998 edition)
DIN EN ISO 11885 (April 1998 issue)
DIN ISO 11047 (May 1998 edition)
Cadmium DIN EN ISO 5961 (May 1995 edition)
DIN EN ISO 11885 (April 1998 issue)
DIN ISO 11047 (June 1995 edition)
Chrome DIN EN 1233 (August 1996 edition)
DIN EN ISO 11885 (April 1998 issue)
DIN ISO 11047 (June 1995 edition)
Copper DIN 38406, part 7 (September 1991 edition)
DIN EN ISO 11885 (April 1998 issue)
DIN ISO 11047 (June 1995 edition)
Mercury DIN EN 1483 (August 1997 edition)
DIN EN ISO 12338 (October 1998 edition).
The results shall be expressed in milligrams per kilogram of dry matter.
1.4.4
Determination of pentachlorophenol (PCP)
1.4.4.1
[0100] Process-based pentachlorophenol and its salts are extracted with methanol in an ultrasonic bath and, after acetylation, are quantified by means of gas chromatography with electron capture detection (GC-ECD). This method is applicable for the determination of PCP in comminuted wood in the concentration range from 0.1 mg/kg to 100 mg/kg.
1.4.4.2
Devices
-
Ultrasonic bath with thermostat
-
Gaschromatograph with electron capture detector and autosampler
1.4.4.3
Chemicals and standards
-
Methanol for residue analysis
-
Cyclohexane and n-hexane for residue analysis
-
Na (deep) 2SO (deep) 4, water-free, granulated
-
PCP as standard in methanolic solution
-
2,4,6-Tribromophenol (TBP) in methanolic solution as internal standard 1 (ISTD 1)
-
PCB 52 as standard in cyclohexane as internal standard 2 (ISTD 2)
-
Acetic anhydride for analysis
-
K (deep) 2CO (deep) 3-solution (0.1 mol/l)
-
Seesand, cleaned
1.4.4.4
Sample preparation measures
1.4.4.4.1
Cleaning of the equipment The cleaning of the glass units is carried out by washing with water and distilled water, as well as rinsing with acetone and n-hexane.
1.4.4.4.2
Preparation of the calibration solutions The stock solutions are prepared by weighing up solid substances of the highest purity and stored at −20 ° C. in the dark.
Concentrations of the stock solutions: PCP in methanol 0.5 mg/ml
TBP in methanol 0.5 mg/ml
PCB 52 in cyclohexane 0.5 mg/ml.
From the stock solutions are diluted by dilution (1:10)
Standard solutions with a concentration of 0.05 mg/ml.
1.4.4.4.3
Calibration The calibration is carried out over the entire process. For this purpose, 20 myl, 50 myl, 100 myl, 200 myl and 500 myl of the standard PCP solution are each added with 250 myl of the standard TBP solution to 5 g of sea sand and worked up as described below for carrying out the analysis (that is to say, instead of wood, Seesand used).

An example of a calibration: Calibration solutionPCP (ng/ml) TBP (ng/ml) ISTD 1PCB 52 (ng/ml) ISTD 2
1 1.0 10.0 20.0
2 2.0 10.0 20.0
3 5.0 10.0 20.0
4 10.0 10.0 20.0
5 20.0 10.0 20.0
1.4.4.5
Sample preparation
1.4.4.5.1
Depending on the concentration to be expected, 1 g, 3 g or 4 g of wood are each weighed into an Erlenmeyer flask. 250 myl TBP solution (ISTD 1) is added to the wood. This solution is allowed to act for 30 minutes. The wood is then treated with 50 ml of methanol and subjected to an ultrasonic treatment at 40 ° C. for two hours. After the solids have been deposited, the extract (about 25 ml) is carefully removed with a pasteurpipette, transferred to a sealable glass vessel and stored for further processing.
1.4.4.5.2
Acetylation In a 150 ml shaking funnel, 30 ml of a 0.1 molar K (deep) 2CO (deep) 3 solution are initially introduced, mixed with an aliquot of the extract (for example 1 ml) and shaken for five minutes. The addition of 2 ml of acetic anhydride is carried out for two minutes. Then add 20 ml of cyclohexane and shake for ten minutes. The aqueous phase is discarded; the organic phase is filtered through a glass column filled with Na (deep) 2SO (deep) 4 into a 25 ml measuring flask. After addition of 10 myl of the solution of the ISTD 2, the mixture is filled to 25 ml. This solution is used for GC-ECD analysis. The PCP concentration in the extract must be within the range covered by the calibration solutions.
1.4.4.6
Analysis using GC-ECDGC conditions (example): Column: HP-5 30 m; 0.25 mym; 0.32 mm ID

20 degrees C/min
Oven temperature: 50 degrees C (1 min) ............ 160 degrees C (0 min)
8 degrees C/min
........... 310 degrees C (5 min)
Detector temperature: 350 degrees C
Injector temperature: 250 degrees C
Injection mode: split/splitless
Carrier gas: H (deep) 2-Column Vordruck (35 kPa)
Make up gas: N (deep) 2 (60 ml/min)
The following measurements shall be carried out:
- Blank values: Device Blind Value (pure cyclohexane)
* Chemical blind value (implementation of the entire procedure without wood sample)
* Analysis of a contamination-free wood
- Calibration solutions
- Sample extracts after the workup described.
For the quality assurance of the analytical results, the recovery rates of the acetylated internal standard 1 (tribromophenol) are to be constantly checked against those of the internal standard 2 (PCB 52).
1.4.4.7
Evaluation
1.4.4.7.1
The first step is to create a calibration straight line with the standard solutions (see section 1.4.4.7.2), followed by the determination of the PCP content in a sample extract by means of this calibration line (see section 4.4). 1.4.4.7.3).
1.4.4.7.2
Calibration over the entire process To create the calibration line, the peak area ratio of acetylated PCP standard to acetylated TBP is plotted against the corresponding concentration ratio in accordance with the following equation:
a (deep) PCP c (deep) PCP
----------- = s x --------------- + b
a (deep) TBP c (deep) TBP
where:
a (deep) PCP measured display of the acetylated PCP standard (for example, peak area)
a (deep) TBP measured indication of the acetylated TBP standard (for example, peak area)
R the slope of the calibration line
c (deep) PCP the mass concentration of the acetylated PCP in the calibration solutions in ng/ml
c (deep) TBP the mass concentration of the acetylated TBP in the calibration solutions in ng/ml
B the ordinate section of the calibration lines
means.
Calculation of the PCP-salary:
The PCP content in the wood sample can be determined according to the following equation from the multipoint calibration straight line:
Content (deep) PCP = a (deep) PCP/aTBP-b c (deep) TBP x f x v: 1000
------------------- x
s x m
where:
Content (deep) PCP Content of PCP in the sample in mg/kg
c (deep) TBP the mass concentration of the TBP in the sample extract in ng/ml
M the mass of the wood used for the extraction in g
a (deep) TBP measured display of the TBP standard in the sample extract (for example, peak area)
a (deep) PCP measured display of the analyzed PCP in the sample extract (for example, peak area)
F the ratio of the total volume of the extract to the volume of the aliquots for derivatization (for example, 50 ml/2 ml = 25)
C the volume of the final solution for analysis in ml (for example 25 ml)
R the slope of the calibration line
B the ordinate section of the calibration lines
means.
1.4.4.7.3
Indication of results The results shall be expressed in milligrams per kilogram of dry matter.
1.4.5
Determination of polychlorinated biphenyls (PCBs) The air-dry, ground altholt sample is extracted after the addition of an internal standard with n-hexane in the soxhlet or by a comparable extraction process. PCB congeners contained in the extract are largely freed from interfering accompanying substances by suitable purification steps, in particular a combination of a benzenesulfonic acid separation column with a silica gel column. The PCB congeners (Ballschmiter No. 28, 52, 101, 138, 153, 180) are determined by capillary gas chromatography with electron capture detector (ECD) in application of DIN 38414, part 20 (January 1996 edition). The total amount of PCBs is calculated from the sum of the mass fraction of each of the PCB congeners, in relation to the dry mass of the alto sample, multiplied by a factor of five and rounded to 0.1 mg/kg. The Federal Ministry of the Environment, For the determination of polychlorinated biphenyls, nature protection and reactor safety can provide other scientifically recognised testing methods in the Federal Gazette if there is a corresponding scientific knowledge.
1.5
Other methods The competent authority shall allow other methods if their equivalence is demonstrated.
2
Indication and calculation of results The results of each of the two parallel determinates and their arithmetic mean shall be indicated. For the purpose of checking compliance with the limit values set out in Annex II, the arithmetic mean value shall be set down. Averaging is only permissible if the difference between the two individual values does not exceed the methodical repeatability according to DIN ISO 5725, Part 1 (November 1997 edition). In the case of such an overrun, a check is required for possible causes of the excessive difference and a third measurement. Provided that the examination of the excessive difference has not provided a clear cause, the average of the three of the three sizes shall be considered for the purpose of checking compliance with the limit values set out in Annex II, in accordance with the individual values (median).
3
Quality assurance and control The examination bodies are obliged to ensure the results of the analysis by means of appropriate measures for internal and external quality assurance according to DIN EN ISO/IEC 17025 (April 2000 issue). This includes, among others, the management of quality control cards, the use of reference materials and successful participation in ring trials.
4
Notices of expert vacancies in ISO standards, EN standards and DIN standards, to which reference is made in this Annex, have been published by Beuth-Verlag GmbH, Berlin and Cologne, and are deposited at the German Patent Office in Munich in terms of their archives.
Unofficial table of contents

Annex V (to § 7)
Analysis of waste wood for energetic utilization

The sampling in accordance with § 7 shall be carried out by persons who have the technical expertise required to carry out the sampling. The samples to be examined can be taken from the current altholt throughput of pre-fractured old wood. In each case at most 10 t of the charge to be tested, at least 20 kg of old wood can be taken out of the material flow via a discharge device. From the altholt sample taken in this way, altholk fractions of unauthorised altholt categories are to be sorted out in accordance with the specifications according to § 5 and the mass of these are to be determined. Unofficial table of contents

Annex VI (to § 11)
Old Timber Delivery Note

Source of the original text: BGBl. I 2002, 3314-3315
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Old Timber Delivery Note
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Deliverer Date:
(Firma/contact person):
Street:
Postal code and location:
Phone:
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Origin of the material:
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Common Altholzsortimente I Allocate I Altholz-I Quantity
I in rule I category I
I to Altholz-I des an-I
I category I delivered I I
I I Altholzes I (t) (cbm)
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Sections, chips of I A I I I I I I I
Natural solid wood I I I I I
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Section, sections, chips of I A II I I I I
Wood-based materials and other I I I I
Treated wood (without harmful I I I I
Impurities) I I I I
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Pallets made of solid wood, such as B.: I A I I I I
Europaletten, Industriepaletten I I I I
Of solid wood I I I I
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Pallets of wood-based materials I A II I I I
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Other pallets, with I A III I I I
Composite materials I I I I
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Transport boxes, Blows from I I I I I I I
Solid wood I I I I
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Transport boxes made of wood-based materials A II I I I
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Fruit, vegetables and ornamental plants-I A I I I I
Boxes and similar boxes of I I I I
Solid wood I I I I
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Ammunition crates I A IV I I I
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Cable drums made of solid wood I A IV I I I
(Production before 1989) I I I I
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Cable drums made of solid wood I A I I I I I
(Production after 1989) I I I I
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Construction site standard from I A I I I I I
Natural solid wood I I I I I
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Building site furniture from wood-I A II I I I I
materials, formwork products, I I I I
Treated solid wood (without I I I I I
harmful impurities) I I I I
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Floorboards, floors, boards-I A II I I I I
formwork from the interior design I I I I I
(without harmful impurities) I I I
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Door leaves and frames of I A II I I I
Interior doors (without damaging I I I I
Impurities) I I I I
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Profile boards for the room-I A II I I I I
equipment, ceiling panels, I I I I
Decorative beams, etc. (without harmful I I I I
Impurities) I I I I
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Insulating and soundproofing plates, I Disposal I I I
which have been treated with appropriations, I I I I
the polychlorinated biphenyls I I I I
I I I I I
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Building panels I A II I I I
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Structural oil for load bearing I A IV I I I
Parts I I I I
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Timber frame and roof rafters I A IV I I I
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Windows, window poles, I A IV I I I I
Exterior doors I I I I
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Impregnated construction timber from the I A IV I I I
External Area I I I I
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Construction and demolition wood with I A IV I I I
Harmful impurities I I I I
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Railway sleepers I A IV I I I
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Line masts I A IV I I I
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Garden and I A IV I I I I I
Landscaping, impregnated I I I I
Garden furniture I I I I
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Agricultural assortments I A IV I I I
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Furniture, natural solid wood I A I I I I I
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Furniture, without halogen-organic I A II I I I I
Compounds in coating I I I I I
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Furniture, with halogen-organic I A III I I I I
Compounds in coating I I I I I
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Waste wood from bulky waste I A III I I I I
(Mixed assortment) I I I I
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Waste wood from industrial I A IV I I I I
Application (e.g. B. Industry-I I I I
Floors, Cooling towers) I I I I
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Waste wood from hydraulic engineering I A IV I I I I
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Waste wood of scrapped ships I A IV I I I
and wagons I I I I
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Waste wood from damage cases I A IV I I I
(e.g. B. Brandholz) I I I I
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Fine fraction from work-up I A IV I I I
From wood to wood-based materials I I I I
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Wood chips, wood shavings I I I I
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Other (more name I I I I I
(hereinafter) I I I I I
I I I
................................. I I I
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Additional information for the
Operators of the AltholzTreaty
plant (where necessary):
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Receiver Street:
(Firma/contact person): PLZ and location:
Phone:
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................................
(Signature of the supplier)
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