379/2000 Sb.
DECREE
The Ministry of industry and trade
of 10 June 1999. October 2000,
laying down the conditions for the determination of individual types of Crystal
glass, their properties and the methods of labelling of products from Crystal
glass
The Ministry of industry and trade shall be determined according to section 28a (e). (f)) of law No.
634/1992 Coll. on consumer protection, as amended by Act No. 103/1995 Coll. and
Act No. 64/2000 Coll.:
§ 1
(1) the Decree lays down the conditions for the determination of each of the species
Crystal glass, including the names of the following species, properties that is
characterize, they added symbols and methods of measurement for the
chemical and physical properties, as well as the conditions for marking
Crystal glass products including the identification of products from Crystal
glass, which are subject to labelling.
(2) the labelling shall apply to the products of each type of Crystal
the glass included in the code number of the harmonised system customs 7013
nomenclature. ^ 1)
(3) the individual types of crystal glass are referred to by these names:
and) highly leaded Crystal 30% PbO,
b) leaded Crystal 24% PbO,
c) crystal glass krystalin, or
d) crystal glass.
(4) the conditions for determining the individual types of crystal glass and the way
marking are listed in annex 1.
(5) the methods for determining the chemical and physical properties of the individual
types of crystal glass are given in annex 2.
§ 2
The name of the type and symbol according to annex No 1 can only be used for individual
types of crystal glass, if they fulfil the conditions laid down in this
the annex.
§ 3
The names of the types of crystal glass and symbols referred to in annex 1,
be placed together on one label.
§ 4
Where commercial designation, name of the manufacturer, importer or seller
or any other mark or part thereof would be identical or
similar with the designation of the individual types of crystal glass under this
the Decree, or would have them give rise to any confusion, both in the
menu and in the commercial documentation, and in the advertising of such products,
marks before the placing on the market in such a way as to
and) for each type of crystal glass, it was possible to conclusively determine
whether they meet the requirements set out in section 2, and
(b)) products that do not meet the requirements referred to under (a)), have not been
bear the symbol and the name of the Crystal glass according to annex No 1;
such product shall be marked in accordance with its properties.
§ 5
The effectiveness of the
This Decree shall enter into force on 1 January 2000. January 1, 2001.
Minister:
doc. Ing. Gregr, r.
Č. 1
The conditions for determining the individual types of crystal glass and the way
their labelling
Č. 2
METHODS OF DETERMINING THE CHEMICAL AND PHYSICAL PROPERTIES OF EACH SPECIES
CRYSTAL GLASS
1.
CHEMICAL ANALYSIS
1.1.
Bao and PbO
1.1.1 establishment of the combination BaO + PbO
In a Platinum dish to the nearest 0.0001 g weigh approximately 0.5 g
gently rozetřeného the glass. After wetting with water, add 100 ml of a 15% solution
10 ml of sulphuric acid and hydrofluoric. Then heat up the sand
bath, to begin to develop white fumes. When cool, add 10 again
ml of hydrofluoric acid and heat until the development of the White
fumes. Allow to cool, the sides of the dish with water and heat,
to begin to develop white fumes. When cool, carefully add 10 ml and
the contents of the bowl into a beaker 400 ml. Rinse the dish several times
10% solution of sulphuric acid and dilute with the same solution to a volume of 100
ml. Solution precipitate boil 2 to 3 minutes. Then allow to stand
for at least 12 hours.
The precipitate is filtered filter crucible of porosity 4 wash
first 10% sulphuric acid solution, then two to three times
with ethyl alcohol. Crucible with precipitate is dried in an oven at 1 hour
150 degrees C weigh the BaSO4 + PbSO4.
1.1.2 establishment of BaO
In a Platinum dish to the nearest 0.0001 g weigh approximately 0.5 g
gently rozetřeného the glass. After wetting with water, add 10 ml of acid
5 ml of hydrofluoric and perchloric acid and heat on the sand bath,
to begin to develop white fumes.
After cooling, add a further 10 millilitres hydrofluoric acid and heat
the development does not occur again until white fumes. Allow to cool and
the walls of the bowl is rinsed with distilled water. Heat again and
evaporate almost to dryness. Dissolve in 50 ml of 10% solution
hydrochloric acid and heat gently to facilitate
dissolving. Transfer the solution into the beaker, 400 ml and dilute with water to
volume 200 ml. Heat until boiling and blows the hot stream of hydrogen sulphide.
The supply of hydrogen sulfide shall cease when the lead sulphide precipitate
falls to the bottom of the beaker. The precipitate is filtered through a fine filter
paper and wash with cold water saturated with hydrogen sulphide.
Bring to a boil the filtrate and then, if necessary, a reduction in volume
by evaporation to 300 ml. To boiling mixture, add 10 ml of 10% solution
sulphuric acid and remove from the heat source. After at least
čtyřhodinovém stall, the precipitate is filtered through a fine filter paper and
wash with cold water. Calcine the precipitate at 1050 ° C and weighed
is BaSO4.
1.2.
Determination Of ZnO
After the separation of BaSO4 filtrate is evaporated to a volume of 200 ml. Neutralise with
ammonia in the presence of methyl red, add 20 ml of sulphuric acid (c) (1/2 H2SO4)
= 0.1 mol/l, [formerly 0, 1N]. The addition of sulphuric acid, c (1/2 H2SO4) = 0.1
mol/l [formerly 0, 1N], or (c) sodium hydroxide (NaOH) = 0.1 mol/l
[formerly 0 71 n], adjust the pH of the solution to a value of 2 for the control of the pH meter.
Cold is placing a stream of hydrogen sulphide precipitates zinc sulphide. After 4
hours of standing, the precipitate is filtered through a fine filter paper and
wash with cold water saturated with hydrogen sulphide. Precipitate on the filter
dissolve by adding 25 ml of hot 10% solution of hydrochloric acid.
Filter with boiling water until it gets about 150 ml of the filtrate. The filtrate
neutralize ammonia in the litmus paper, then add 1-2 g
solid urotropine to the value of the pH of the solution should be approximately 5. Add
a few drops of freshly prepared aqueous solution of xylenol 0.5%
Orange and Titrate with sodium complexone III c (C10 H14 N2 Na2 O8.2H2O)
= 0.1 mol/l, [formerly 0, 1N] until the color transition from pink to lemon
yellow.
1.3
Determination Of K2O
K2O is determined by precipitation and weighing of potassium as tetrafenylboritan.
In a Platinum dish to the nearest 0.0001 g weigh about 2 g
the crushed and prosátého glass, add 2 ml of concentrated HNO3
(nitric acid), 15 ml of HClO4 (perchloric acid) and 25 ml HF
(hydrofluoric acid). Heat the water, and then on the sand
the bath. After their dense white fumes perchloric acid is
evaporate to dryness. Dissolve the addition of 20 ml of hot water and 2-
3 ml of concentrated HCl. Transfer the solution into a 200 ml volumetric flask and
make up to the mark with distilled water.
Reagents: 6% solution of sodium tetraphenylborate: dissolve 1.5 g
the reagent in 250 ml of distilled water, any light turbidity is removed
by adding 1 g of alumina. Shake for 5
minutes and filter, with the first 20 millilitres obtained again
filter.
Washing solution for the precipitate: a small amount of the potassium salt is prepared
so that in a solution of 0.1 g of KCl in 50 ml of hydrochloric acid (HCl) c
= 0.1 mol/l, [formerly 0, 1N] adds stirring the solution
of sodium tetraphenylborate to their formation of a clot. The precipitate is
filter on frit, washed with distilled water and dry in a desiccator
at room temperature. Then add 20-30 mg of the precipitate to 250
ml of distilled water and mix. After 30 minutes, add 0.5-1
(g) alumina, stir a few minutes and then
filter.
Workflow: an aliquot after acid decomposition of the corresponding
approximately 10 mg of K2O is diluted to about 100 ml., stirring
slowly add about 10 ml of precipitating agent on every
the anticipated 5 mg of K2O. Leave to stand for no more than 15 minutes, then
filter on the advance zváženém crucible of porosity 3 or 4.
Wash with washing solution and dry 30 minutes at 120 degrees C.
Conversion factor for K2O is 0.13143.
1.4.
Tolerances
1.4.1. For the determination of any of the folders is the tolerance +/-0.1
absolute values.
1.4.2 If analysis within the tolerances, the value of the
lower than the fixed limit (30, 24, or 10%), average
from at least 3 analyses. If this average is greater than or equal to 29.95, glass
be included in the category corresponding to 30%, is higher than or equal to 23.95,
the glass shall be classified in categories corresponding to 24% and is higher than or equal to
9.95, glass is included in the category corresponding to 10%.
1.5
Other methods of chemical analysis
For the chemical analysis of the Crystal glass can be used as well as other appropriate
analytical methods, if they are proven to meet the requirements for
precision and accuracy of the results of measurement defined by subsection 1.4.1.
When you use multiple methods of measurement, or in the case of measuring according to the disputing
the first sentence is a decisive result, the one that was obtained using the methods
referred to in points 1.1 to 1.3.
2.
DETERMINATION OF PHYSICAL PROPERTIES
2.1
The density of the
It is determined by Hydrostatic weighing with an accuracy of +/-0.01. Sample
of not less than 20 g shall be weighed in the air and then weigh the steeped
in distilled water at a temperature of 20 ° C.
2.2.
Index of refraction
The index is measured by refractometer to within +/-0.001.
2.3.
Microhardness
The Vickers hardness test with a load of 50 g.
taking the average of the 15.
1) Decree of the Minister of Foreign Affairs No. 160/1988 Coll., on International
Convention on the harmonized commodity description and coding of goods and
Protocol of amendment thereto.
§ 56 et seq. Act No. 13/1993 Coll. Customs law.
Government Regulation No. 318/1999 Coll., implementing the customs tariff.
