29/1998 Coll.
The COMMUNICATION FROM the
Ministry of Foreign Affairs
Change: 60/1999.
Ministry of Foreign Affairs declares that the joint meeting of experts
International railway regulations for transport of dangerous goods (RID) and
The European Agreement concerning the international carriage of dangerous goods
(ADR), which was held in Geneva on 16 and 17. -20. September 1996, were
accepted amendments annex I-regulations for international rail
transport of dangerous goods (RID) Connection B-uniform rules
the contract of international carriage of goods by rail (CIM) to the Convention on
international carriage by rail (COTIF), adopted in Bern on 9. may
1980. ^ 1)
Amendments to annex I-regulations concerning the international carriage of
dangerous goods Connection (B) entered into force on 1 January 2000. January 1997 and
that date also have entered into force for the Czech Republic.
Czech translation of the full text of annex I-regulations for international rail
transport of dangerous goods shall be delivered at the same time.
Convention concerning international carriage by rail (COTIF)
Hook-B-uniform rules concerning the contract of international
the carriage of goods by rail (CIM)
Annex I To The
REGULATIONS CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS (RID)
PART I
Cancelled
Cancelled
PART II
Cancelled
Class 1
Cancelled
1.
Cancelled
Class 2
Cancelled
1.
Cancelled
200
(1) substances and articles that belong under the concept of class 2, shall be subject to under the
This notion of those substances and articles, which are listed in section 201 or
fall under, collectively referred to in this paragraph and shall be subject to such
the conditions set out in paragraphs (2) to 200 250 are substances and articles
RID (PNZ).
Editor's note.
The quantities for substances referred to in paragraph 201, as well as for items that
are not subject to the section "conditions of carriage", see section 201a.
(2) Gases are substances that
and at 50th.) C have a vapour pressure greater than 300 kPa (3 bar), or
(b)) at 20th. C and a standard pressure of 101.3 kPa are completely gaseous.
Editor's note.
1052 hydrogen fluoride is a substance of class 8 (see Section 801, number 6).
(3) Class 2 contains pure gases, mixtures of gases, mixtures of one or more
gases with one or more other substances, as well as items that
such substances include.
Editor's note.
1. Clean gas may contain other ingredients that come from the production
the process, or that are added to ensure the stability
product, provided that the concentration of these components does not change the classification
or conditions of carriage as the degree of filling, filling pressure or test
the excess pressure.
2. the name j.n. in section 201 include how to clean gases as well as mixtures.
3. for the classification of solutions or mixtures (such as preparations, products and
wastes), see also section 3 (3), as well as paragraphs (6) and (7) of this section.
(4) the substances and articles of class 2 are subdivided as follows:
1. Compressed gases: Gases having a critical temperature below 20th. (C)
2. Liquefied gases: Gases having a critical temperature of 20th. C or higher
3. deeply refrigerated liquefied gases: gases which, because of their low
the temperature of the liquid during transport are partially
4. Under pressure dissolved gases: Gases, which, during transport
dissolved in a solvent
5. Packaging on aerosols
6. other items that contain gas under pressure
7. the Gases, which are not under pressure, subject to special conditions
(gas sampling)
8. Empty containers
(5) substances and articles, which are listed under different numbers point 201,
According to their hazardous properties are assigned to one of the
the following groups of "^ 1"):
And the suffocating
Oxidising
F flammable
T toxic
TF toxic, flammable
TC toxic, corrosive
THIS toxic, oxidizing
TFC toxic, flammable, corrosive
TOC toxic, oxidizing, corrosive
Editor's note. Corrosive gases are considered to be toxic and
Therefore, they are classified in the Group TC, TFC or TOC see
paragraph (7).
If gases or mixtures of gases are hazardous properties that can be
to assign more than one group, those groups marked with the letter T
precedence over all other groups. The group marked with the letter F
take precedence over groups designated by letters A or O.
(6) if one digit and the group namely referred to a mixture of class 2
It seems according to the criteria referred to in paragraphs (4) and (7) under a different
number and/or another group, so it is necessary to appropriately classify this mixture according to the
These criteria and to include appropriate indications n.e.c.
(7) the substances and articles not mentioned in paragraph 201, namely should be included
According to subsection (4) and (5).
Appropriately according to their hazardous properties, the following criteria:
Stifling gases
Gases which are flammable, oxidising and are not poisonous and that
in air under normal conditions, the existing oxygen zřeďují or
vypuzují.
Flammable gases
Gases which at 20th. C and a standard pressure of 101.3 kPa
and in the mix for a maximum) 13 vol-% gas in air is combustible, or
b) independently from the lower explosive limit are reaching the area of explosion,
the air of at least 12 percentage points.
Flammability must be determined with the help of experiments or calculations according to methods
approved by ISO (see ISO 10156:1990 standard).
Where, for the use of these methods are available only to the lack of
the data may be used by tests in accordance with comparable methods, if they are
accepted by the competent authority of the country of origin.
If the country of origin is not a Member State of COTIF, these methods must be recognized
the competent authority of the first COTIF Member State, which will come into contact
with the shipment.
Oxidising gases
Gases which can cause or, in General, support the burning
other substances with the help of oxygen more efficiently than air. The ability to
oxidation must be determined with the help of experiments or calculations according to the methods
approved by ISO (see ISO 10156:1990 standard).
Toxic gases
Editor's note.
Gases, which due to their corrosion partially or completely correspond to the
criteria for toxicity, are to be classified as toxic. Due to a possible
Similarly, the risk of corrosion, see also the criteria under the heading "Corrosive
gases ".
Gases,
and) which are known to have such a poisonous or corrosive effect on
man, that constitute a danger to human health; or
(b)) which are deemed to have toxic or corrosive effect on
the man, because the test according to section 600 (3) reported an LC50 value for the
acute toxicity of not more than 5000 ml/m3 (ppm).
For the classification of mixtures of gases (including vapours of substances of other classes) can be
use the following formula:
LC50 (mixture) = Ivy
While
fi = molový a fraction of the i-th part of the mixture
TI = a number to denote the i-th part of the toxicity of the mixture.
You value matches the value of LC50 from ISO
10298:1995. If LC50 is not in ISO
10298:1995 listed, you must use the value of LC50,
that is mentioned in the scientific literature. If the value of
LC50 is unknown, the number to indicate
virulence on the basis of the lowest LC50 value of substances
with similar physiological and chemical properties,
or, if that is the only option, based on experiments.
Corrosive gases
Gases or gas mixtures, which due to its corrosive effects completely
match the criteria for toxicity, are to be classified as toxic with a
the additional danger corrosive.
A mixture of gases, that is, for reasons of caustic effect and toxicity is considered
for poisonous, contains additional danger caustic effect, if
through the verified values in relation to humans is known to be
a mixture of harmful to the skin, eyes or mucous membranes or when the LC50
corrosive mixture when calculating the parts according to the following formula, not more than
5000 ml/m3 (ppm):
LC50 (mixture) = Ivy
While
FCI = molový a fraction of the ith corrosive part mixture
TCI = number to denote the ith corrosive virulence parts
the mixture. Tci value matches the value of LC50 according to
ISO 10298:1995. If LC50 is not in ISO
10298:1995 listed, you must use the value of LC50,
that is mentioned in the scientific literature. If the value of
LC50 is unknown, the number to indicate
virulence on the basis of the lowest LC50 value of substances
with similar physiological and chemical properties,
or, if that is the only option, based on experiments.
(8) the chemically unstable substances of class 2, shall not be made for transportation
then, if it was taken the necessary measures to prevent all possibility of
Hazardous reactions under normal conditions of carriage, such as.
Disproportionation or decomposition, polymerization. To this end, it is particularly
care should be taken that the containers do not contain substances which these reactions
encourage
201
1. Compressed gases: Gases having a critical temperature below 20th. (C).
Numbers and Number to indicate the substance, naming and
Group description
-------------------------------------------------------------
1 and the stifling fumes (or gases
do not show additional hazards)
1002 air, compressed (compressed air)
1006 argon, compressed
1046 helium, compressed
1056 krypton, compressed
1065 neon, compressed
1066 nitrogen, compressed
1979 rare gases mixture, compressed
1980 rare gases and oxygen mixture,
compressed
1981 rare gases and nitrogen mixture,
compressed
1982 tetrafluormethan, compressed (gas
as a refrigerant, R14,
compressed)
2036 xenon, compressed
2193 (hexafluorethan, compressed gas as a
refrigerant, R116, compressed)
1956, compressed gas, n.o.s.
Editor's note. 1. Mixtures containing more than 21% oxygen by volume-is
to be classified as oxidizing.
2. Air and other mixtures used for the purpose of breathing
are not considered to be suffocating.
3. A mixture of numbers to indicate the substance of the 1979, 1980 and 1981
must not contain more than 10% Xenon.
1 for oxidizing gases
1014 oxygen and carbon dioxide, mixture,
compressed
Editor's note. A mixture of numbers to indicate the substance
1014 shall not contain
more than 30% carbon dioxide.
1072 oxygen, compressed
3156, compressed gas, oxidizing, n.o.s.
1 F flammable gases
1049 hydrogen, compressed
1957 deuterium, compressed
1962, ethylene, compressed
1971 methane, compressed or
1971 natural gas, compressed with high
methane content
2034 hydrogen and methane mixture, compressed
2203 Silane, compressed
Editor's note. 2203 Silane, compressed is
considered as pyrophoric
(pyroforický)
in 1964, a mixture of gaseous hydrocarbons,
compressed, n.o.s.
1954 gas compressed, flammable, n.o.s.
1 T toxic gases
1612 hexaethyltetrafosfát and compressed
gas mixture
1955 gas compressed, poisonous, n.o.s.
1 TF toxic flammable gases
1016 carbon monoxide, compressed
1023 coal gas, compressed
1071 oil gas, compressed
1911 diboran, compressed
2600 carbon monoxide and hydrogen mixture,
compressed (synthesis gas, water
gas, Fischer-Tropsch)
1953 compressed gas, toxic,
flammable, n.o.s.
1 TC toxic corrosive gases
1008 boron trifluoride, compressed
1859 silicon fluoride, compressed
2198 pentasulphide fluoride, compressed
2417 Carbonyl fluoride (karbonylfluorid),
compressed
3304 compressed gas, toxic,
corrosive, n.o.s.
1 this poisonous oxidising gases
2451 nitrogen trifluoride, compressed fluoride
3303 compressed gas, toxic,
oxidizing, n.o.s.
1 TFC toxic flammable corrosive gases
3305 compressed gas, toxic,
flammable, corrosive, n.o.s.
1 TOC toxic corrosive oxidizing gases
1045 fluorine, compressed
1660 nitric oxide, compressed
2190 Oxygen fluoride, compressed
3306 compressed gas, toxic,
oxidizing, corrosive, n.o.s.
2. Liquefied gases: Gases having a critical temperature of 20th. C or higher
------------------------------------------------------------------
Digits, and the Number to the labelling of the substance, the naming and description
Group
------------------------------------------------------------------
2 and suffocating gases
1009 Bromotrifluoromethane (Refrigerant gas as
resource R13B1)
1013 carbon dioxide
1015 carbon dioxide and nitrous oxide mixture
1018 chlordifluormethan (gas as the cooling
means of R22)
chlorpentafluorethan (1020 gas as
refrigerant R115)
1021 1-chloro-1, 2, 2, 2-tetrafluoroethane (gas
as refrigerant R124)
1022 chlortrifluormethan (gas as
refrigerant R13)
1028 dichlordifluormethan (gas as
refrigerant R12)
1029 dichlorfluormethan (gas as the cooling
resource R21)
1058 gases liquefied, nezápalné,
overlaid with nitrogen, carbon dioxide or
air
1080 sulphur hexafluoride
1858 hexafluorpropylen (gas as the cooling
resource R1216)
1952 ethylene oxide and carbon dioxide mixture,
containing not more than 9% ethylene-oxide
1958 1.2-dichlortetrafluorethan (gas as
R114 refrigerant)
1973 chlordifluormethan and
chlorpentafluorethan, mixed with
constant boiling point, with approximately 49%
chlorodifluoromethane (Refrigerant gas as
resource is R502)
1974 bromochlorodifluoromethane (gas as
refrigerant R12B1)
1976 oktafluorcyklobutan (gas as
refrigerant RC318)
1983 1-chloro-2, 2,2-trifluoroethane (gas as
refrigerant R133a)
1984 trifluormethan (gas as the cooling
resource R23)
2422 oktafluor-2-butene (gas as the cooling
resource R1318)
2424 oktafluorpropan (gas as the cooling
resource R218)
2599 chlortrifluormethan and trifluormethan,
azeotropic mixture with approximately 60% of the
chlortrifluormethanu (gas as
R503 refrigerant)
dichlordifluormethan and 1.1-2602
difluorethan, azeotropic mixture with approximately 74%
dichlorodifluoromethane (gas as
refrigerant R500)
3070 ethylene oxide and dichlordifluormethan,
mixture with not more than 12.5% ethylene oxide
3159 1, 1, 1, 2-tetrafluoroethane (gas as
REFRIGERANT R134a)
3220 pentafluorethan (gas as the cooling
resource R125)
3296 heptafluorpropan (gas as the cooling
resource R227)
3297 ethylene oxide and chlortetrafluorethan,
mixture with not more than 8.8% ethylene oxide
3298 ethylene oxide and pentafluorethan, mixed with
not more than 7.9% ethylene oxide
3299 ethylene oxide and tetrafluoroethane mixture with
not more than 5.6% ethylene oxide
1078 gas as a refrigerant, n.e.c.
as the gas mixture with the designation R...,
they have such as:
mixture F1 at 70th. (C) vapour pressure
not exceeding 1.3 MPa (13 bar) and at 50
St. (C) density, which corresponds to a minimum
the density of the dichlorfluormethanu (1.30 kg/l)
mixture F2 at 70th. (C) vapour pressure
not exceeding 1.9 MPa (19 bar) and at 50
St. (C) density, which corresponds to a minimum
the density of dichlorodifluoromethane (1.21
kg/l)
mixture F3 at 70th. (C) vapour pressure
not exceeding 3 MPa (30 bar) and when
50th. (C) density, which corresponds to the
a minimum density of chlorodifluoromethane
(1.09 kg/l)
Editor's note. Trichlorfluormethan (cooling
means of R11), 1, 1, 2-trichloro-
1, 2, 2-trifluoroethane (refrigerant
resource R113), 1, 1, 1-trichloro-
2, 2, 2-trifluoroethane (refrigerant
resource R113a), 1-chloro-2,2-1
trifluoroethane (refrigerant
R133) and 1-chloro-1, 1,2-trifluoroethane
(cooling resource R133b) are not
substances of class 2. However, they may be
parts of mixtures F 1 to F 3.
1968 insecticide gas, n.o.s.
3163 liquefied gas, n.o.s.
Editor's note. 2455 methylnitrit is not accepted for carriage.
2 on the oxidizing gases
1070 nitrous oxide (laughing gas)
3157 liquefied gas, oxidizing, n.o.s.
2 F flammable gases
1010 1.2-butadiene, stabilized or
1010 1.3-butadiene, stabilized or
1010 1.3-butadiene and hydrocarbons, mixtures,
stabilized to 70th. (C)
vapour pressure not exceeding 1.1 MPa (11
bar) and whose density do at 50
St. (C) under the value of 0.525 kg/l;
Editor's note. In containers with 1.2-butadienem can
oxygen concentration
in the gas phase shall not exceed 50 ml/m3
1011 butane
1012 buteny, mixture or
1012 1-butene or
1012 2-butene cis or
1012 2-butene trans
1027 cyclopropane
1030 1.1-difluorethan (gas as the cooling
resource R152a)
1032, anhydrous;
1033 dimethyl ether
1035 Ethane
1036 ethylamine
1037 ethyl chloride (ethylchlorid)
1039 ethylmethylether
1041 ethylene oxide and carbon dioxide mixture with
more than 9% but not more than 87% ethylene oxide
1055 isobuten
1060 methylacetylen and propadien, mixture,
stabilized as a mixture of methylacetylenu and
propadienu with hydrocarbons, which are:
mixture P 1 containing not more than 63 vol-%
methylacetylenu and propadienu and not more than
24. vol.-% propane and propene-rich; While
the percentage of saturated
hydrocarbons, C4 fraction must be at least
14. vol.-%,
mixture P 2 containing 48 vol-%
methylacetylenu and propadienu and not more than
50. vol.-% propane and propene-rich; While
the percentage of saturated
hydrocarbons, C4 fraction must be at least 5
Vol-%;
as well as a mixture of propadienu with 1% to 4%
methylacetylenu
1061 methylamine, anhydrous
1063 chloromethane (methylchlorid) (gas as
refrigerant R40)
1077 propen
1081 tetrafluorethylen, stabilized
1083 trimethylamin, anhydrous
1085 vinylbromid, stabilized
1086 vinyl chloride, stabilized
1087 vinylmethylether, stabilized
1860 vinylfluorid, stabilized
1912 chloromethane (methylchlorid) and
dichloromethane, the mixture
Editor's note. If the mixture is not flammable, it must be
assign to the number 2A number of labelling of the substance
3163.
1959 1.1-difluorethylen (gas as the cooling
resource R1132a)
1969 Isobutane
1978 Propane
2035 1, 1, 1-trifluoroethane (gas as
R143a refrigerant)
2044 2.2-dimethylpropan
2200 propadien, stabilized
2419 bromtrifluorethylen
2452 ethylacetylen, stabilized
2453 fluorethan (ethylfluorid) (gas as
refrigerant R161)
2454 fluormethan (methylfluorid) (gas as
refrigerant R41)
2517 1-chloro-1.1-difluorethan (gas as
R142b refrigerant)
2601 cyklobutan
3153 perfluor (methyl vinyl) ether
3154 perfluor (ethylvinyl) ether
3252 difluormethan (gas as the cooling
resource R32)
1965 hydrocarbon gas mixture,
liquefied, n.o.s.,
that has as a
blend and at 70th. (C) the vapour pressure of not more than 1.1
MPA (11 bar) and at 50th. (C) the density of the
at least 0.525 kg/l,
blend and about 70th. (C) the vapour pressure of not more than
1.6 MPa (16 bar) and when
50th. (C) the density of at least 0.495 kg/l,
blend and 1 at 70 degrees. (C) the vapour pressure of not more than
2.1 MPa (21 bar) and at 50th. (C) the density of the
at least 0.485 kg/l,
mixture B at 70th. (C) the vapour pressure of not more than 2.6
MPA (26 bar) and at 50th. (C) the density of the
at least 0.450 kg/l,
mixture C at 70 degrees. (C) vapour pressure not exceeding 3.1
MPA (31 bar) and at 50th. (C) the density of the
at least 0.440 kg/l.
Editor's note. 1. For the above mentioned mixtures are
also eligible as labelling of substances
the following business naming:
for a mixture of A and n-butane, and 0 for a mixture C
propane.
2. If preceded or
the following is by sea or air
transport, may be for the 1965
hydrocarbon gas mixture,
liquefied, n.o.s. used record
1075 petroleum gases, liquefied.
3161 liquefied gas, flammable, n.o.s.
2 tonnes of toxic gases
1062 bromomethane (methyl bromide)
1581 chlorpikrin and bromomethane
(methyl bromide),
1582 chlorpikrin and chloromethane
(methylchlorid), a mixture of
sulfuryl fluoride 2191 (sulfurylfluorid)
1967 insecticide gas,
poisonous, n.o.s.
3162 liquefied gas, toxic, n.o.s.
2 TF toxic flammable gases
1026 cyanogen
1040 ethylene oxide or
1040 ethylene oxide with nitrogen up to a maximum
the permissible total pressure of 1 MPa (10
bar) at 50th. (C)
1053 hydrogen sulphide
1064 methanthiol (methylmerkaptan)
1082 chlortrifluorethylen, stabilized
(trifluorchlorethylen, stabilized)
2188 arzenovodík (arsin)
2192 germanovodík (german)
2199 hydrogen phosphide (fosfin)
2202 selenovodík, anhydrous
2204 Carbonyl sulphide (karbonylsulfid)
2676 antimonovodík (stibin)
3300 ethylene oxide and carbon dioxide mixture with
more than 87% ethylene oxide
3160 liquefied gas, toxic, flammable, n.o.s.
Editor's note. germanovodík (german) 2192 and 2199 hydrogen phosphide (fosfin)
shall be deemed liable to spontaneous combustion (pyrophoric).
2 TC toxic corrosive gases
1005 ammonia, anhydrous ammonia
1017 chlorine
1048 bromovodík, anhydrous
1050 Hydrogen chloride, anhydrous
1069 nitrosylu chloride (nitrosylchlorid)
1076 phosgene
1079 sulphur dioxide
1589 chlorkyan, stabilized
1741 boritý chloride
2194 selenium fluoride
2195 telurový fluoride
2196 tungsten fluoride
2197 jodovodík, anhydrous
2418 sulphur fluoride
2420 hexafluoraceton
3057 trifluoracetylchlorid
3308 liquefied gas, toxic, corrosive, n.o.s.
2 this poisonous oxidising gases
3083 perchlorylfluorid
3307 liquefied gas, toxic, oxidizing, n.o.s.
2 TFC toxic flammable corrosive gases
2189 dichlorosilane,
2534 methylchlorsilan
3309 liquefied gas, toxic, flammable, corrosive,
n.e.c.
2 TOC toxic corrosive oxidizing gases
1067 nitrogen dioxide
1749 chloritý fluoride (chlortrifluorid)
1975 Nitric oxide and nitrogen dioxide mixture
2548 chlorečný fluoride (chlorpentafluorid)
2901 bromine chloride (bromchlorid)
3310 liquefied gas, toxic,
oxidizing, corrosive, n.o.s.
Editor's note. 2421 carbon nitrogen trifluoride is not accepted for carriage.
3. deeply refrigerated liquefied gases: gases which, because of their
low temperature during transport are partially liquid
Editor's note. Deeply refrigerated liquefied gases, which cannot be
assign one of the numbers to indicate the substance of this digit,
are not admitted for carriage.
Digits, and the Number to the labelling of the substance, the naming and description
Group
-------------------------------------------------------------
3 and suffocating gases
1913 neon, deeply refrigerated, liquefied
1951 argon refrigerated liquid, deeply,
1963 helium, refrigerated, liquid deeply
1970 krypton refrigerated liquid, deeply,
1977 nitrogen, deeply refrigerated, liquid
2187 carbon dioxide, refrigerated, deeply
liquid
2591 xenon refrigerated liquid, deeply,
3136 trifluormethan, deeply refrigerated,
liquid
3158 gas refrigerated liquid, deeply, n.e.c.
3 on the oxidizing gases
1003 air refrigerated, liquid, deeply
1073 oxygen, refrigerated liquid,
2201 nitrous oxide, deeply refrigerated, liquefied
3311 gas refrigerated liquid, deeply,
oxidizing, n.o.s.
3 F flammable gases
1038 ethylene refrigerated liquid, deeply,
1961 ethane refrigerated liquid, deeply,
1966 hydrogen, refrigerated, liquid deeply
1972 methane refrigerated liquid, deeply,
or
1972 gas natural, deeply refrigerated,
liquid with high methane content
3138 Ethylene, acetylene and propylene mixture,
deep, liquid cooled with at least
71.5% ethylene, not more than 22.5% acetylene
and not more than 6% propylene
3312 gas refrigerated liquid, deeply,
flammable, n.o.s.
3 TC toxic corrosive gases
Editor's note. 2186 hydrogen chloride, deeply refrigerated, liquid is not accepted
for carriage.
4. Under pressure dissolved gases: Gases that are being
the transport of dissolved in a solvent
Editor's note. Under pressure dissolved gases, which cannot be assigned to
one of the numbers to indicate the substance of this digit, are not
admitted to the transport.
Digits, and the Number to the labelling of the substance, the naming and description
Group
------------------------------------------------------------------
4 and suffocating gases
2073 ammonia (ammonia), the aqueous solution
less than density 0.880 kg/l at 15
St. (C), with more than 35% but not more than 50% of the
ammonia
Editor's note. 2672 ammonia solution (ammonia) with at least 10% and not more than
35% ammonia is a substance of class
8 see Section 801 numbers 43c).
4 F flammable gases
1001 acetylene, dissolved
4 TC toxic corrosive gases
3318 ammonia (ammonia), the aqueous solution
less than density 0.880 kg/l at 15
St. (C), with more than 50% ammonia
5. Packaging on aerosols (see also section 201a)
Editor's note. 1. The packaging of the aerosols are containers that cannot be re-used
to perform, which contain a gas or a mixture of gases under the
with or without liquid, pasty or powdery
the substances which are listed in section 207 (3), and which are
equipped with a valve that allows the collection
emptying the contents in the form of a suspension of solid or
liquid parts in a gas, as a foam, paste or
powder or in liquid or gaseous state.
2. The packaging of the aerosols are containers that cannot be
again to perform, which contain a gas or a mixture of
gases under pressure, which is listed in section 207 (3), and
(4) can be equipped with or without removal of the valve.
3. The packaging of the aerosols should be classified according to the content
the appropriate risk group in the groups and to the TOC.
Content is considered to be inflammable, if this
contains more than 45 m-% or more than 250 g
ignition components. Incendiary ingredients means gases,
that are in the air at ambient pressure for ignition
or substances or preparations in liquid form which have a
Flash point not more than 100th. (C).
Digits, and the Number to the labelling of the substance, the naming and description
Group
----------------------------------------------------------------
5 and suffocating gases
1950 aerosol packaging under pressure
2037 packagings for aerosols with gas, without
removal of the valve, which cannot be re-used
to fulfil the
5 on the oxidizing gases
1950 aerosol packaging under pressure
2037 packagings for aerosols with gas, without
removal of the valve, which cannot be re-used
to fulfil the
5 F flammable gases
1950 aerosol packaging under pressure
2037 packagings for aerosols with gas, without
removal of the valve, which cannot be re-used
to fulfil the
5 tonnes of toxic gases
1950 aerosol packaging under pressure
2037 packagings for aerosols with gas, without
removal of the valve, which cannot be re-used
to fulfil the
5 TF toxic flammable gases
1950 aerosol packaging under pressure
2037 packagings for aerosols with gas, without
removal of the valve, which cannot be re-used
to fulfil the
TC toxic corrosive gases 5
1950 aerosol packaging under pressure
2037 packagings for aerosols with gas, without
removal of the valve, which cannot be re-used
to fulfil the
5 this poisonous oxidising gases
1950 aerosol packaging under pressure
2037 packagings for aerosols with gas, without
removal of the valve, which cannot be re-used
to fulfil the
5 TFC toxic corrosive flammable gases
1950 aerosol packaging under pressure
2037 packagings for aerosols with gas, without
removal of the valve, which cannot be re-used
to fulfil the
5 TOC toxic corrosive oxidizing gases
1950 aerosol packaging under pressure
2037 packagings for aerosols with gas, without
removal of the valve, which cannot be re-used
to fulfil the
6. other items that contain gas under pressure
Digits, and the Number to the labelling of the substance, the naming and description
Group
----------------------------------------------------------------
6 and suffocating gases
1044 Fire extinguishers to appliances
compressed or liquefied gas
2857 refrigerating machines with nezápalným and
lyocell with liquefied gas or with
ammonia solution (numbers to indicate the
substance 2672)
3164 articles under pneumatic pressure (with
nezápalným gas)
3164 articles under hydraulic pressure (with
nezápalným gas)
6 F flammable gases
1057 lighters (cigarette), a Flash
gas or
containers with 1057 lighter refills
(cigarettes), incendiary gas
3150 devices, small gaseous hydrocarbons,
with the valve collection
opakovaněplnitelné container for 3150
small appliances with gaseous hydrocarbons, with
eShop fulfilment valve
7. the Gases, which are not under pressure, subject to specific
conditions (gas sampling)
------------------------------------------------------------------
Digits, and the Number to the labelling of the substance, the naming and description
Group
7 F flammable gases
3167 a gas sample, which is not under pressure,
n.e.c. not deeply chilled
liquid
7 tonnes of toxic gases
3169 a gas sample, which is not under pressure,
poisonous, n.o.s., that is not deeply
the cooled liquid
7 TF toxic flammable gases
3168 a gas sample, which is not under pressure,
toxic, flammable, n.o.s., which is not
deeply refrigerated liquid
8. Empty containers
Digits, and the Number to the labelling of the substance, the naming and description
Group
-----------------------------------------------------------------
8 uncleaned empty containers in accordance with section 211,
uncleaned empty tank wagons,
empty uncleaned battery wagons, wagons with
non-cleaned empty removable
bulk cargo and non-cleaned empty
nádržkovými containers that contain
substances of class 2.
Editor's note. 1. For uncleaned empty receptacles, uncleaned empty
uncleaned empty tank wagons, battery wagons, wagons with
non-cleaned empty removable reservoirs or
uncleaned empty cistern containers are considered to be
those that after emptying from the substances of this class yet
include their small remnants.
2. empty containers, uncleaned, which have contained substances
of this class are not subject to the conditions of RID/PNZ, and if
appropriate measures are taken to eliminate possible
danger. Potential hazards are excluded if
measures are taken to remove the hazard classes 1
up to 9.
201a
Out in paragraph (3) referred to the conditions, are not subject to section 2 "shipping
the terms ":
(1) Gases and articles that are submitted for carriage subject to the following
terms and conditions:
Editor's note.
Gases in tanks of means of transport used for the propulsion, or
operation of their specific equipment (e.g.. cooling equipment),
subject to section 2, "conditions of carriage".
a) gases digits 1A, 1O, 2A and 2 on, the pressure in the vessel or tank
at 15th. (C) does not exceed 200 kPa (2 bar) and which remain within the
completely gaseous transport this refers to all kinds of containers or
tanks, for example. also components of machinery and equipment parts
(b)) 1013 carbon dioxide and a 2-digit or 2-digit 1070 nitrous oxide of, in
gaseous state with not more than 0.5% air, in metal capsules (sodors,
sparklets) section 205 with not more than 25 g carbon dioxide or nitrous oxide
and not more than 0.75 g carbon dioxide or nitrous oxide per cm3 volume
(c) gases in the tanks to be transported) for motor vehicles; operating valve
between the tank and engine shall be closed and the electric contact is interrupted;
d) gases in the parts of the equipment used for the operation of the vehicle (e.g. fire extinguishers
the appliance or gas-filled tires of vehicles, also as a substitute
parts, or as transported cargo);
e) gases in special vehicles, devices that are necessary for the operation
the following special equipment during transport (cooling equipment, tanks
for fish, the apparatus for heating, etc.), as well as the replacement of the tank
such equipment and uncleaned empty containers used to Exchange,
that are transported in the same vehicle;
f) uncleaned empty stationary pressure vessels that are transported,
assuming that they are tightly closed;
g) items 5 and digits, 5 and 5 (F) of a capacity not exceeding 50 cm3;
h) 2857 refrigerating machines of 6 digits and that contain less than 12 kg
a 2-digit gas and or 2073 ammonia solution digits 4 and and similar
the device, containing less than 12 kg gas of 2-digit (F); These machines
must be so protected and loaded, in order not to damage the cooling
System;
I) gases of digits 3 and, for example. the cooling of medical or biological
samples, if contained in double wall receptacles, which
meet the conditions of section 206 (2));
(j)) the following items of number 6, and manufactured and filled according to the regulations
country of the producer, packed in a strong outer packaging:
1044 Fire extinguishing device, if they are provided with protection against
unintentional activation;
3164 articles under the pneumatic or hydraulic pressure against
load on the internal pressure of the gas are for reasons of force transfer, retention
forms or making of předimensovány;
k) gases contained in foodstuffs or beverages.
(2) Gases and articles which will be transported under the following
terms and conditions:
and the digit 1 and gases), and 2, 3 and 4, in containers of a capacity not exceeding 120 ml
fulfilling the conditions of paragraph 202,
(b) articles 5 digits) T, TF, TC 5 5, 5, 5 5 TOC and TFC volume
not more than 120 ml which meet the conditions of paragraph 202,
(c) the digits 5 and) subjects, 5 and 5 (F) of not more than 1000 ml
meet the conditions of 202 points, 207 and 208.
These shall be packed:
I) in an outer packaging that meet at least the requirements of point 1538.
Gross weight of the piece must not be greater than 30 kg; or
II) in shrink or stretch packaging materials (called.
"trays"). Gross weight of the piece must not be greater than 20 kg.
Care should be taken to the "General provisions for the packing of" 1500 point (1), (2) and
(5) to (7).
(3) in the carriage in accordance with paragraph (2) must be a description of the goods in the consignment
the worksheet correspond to the terms of section 226, and must include the term "limited
the amount of ". Each piece must be clearly and durably marked with the number to
labelling of a substance that is listed in the cargo letter, before which make up
the letters "UN".
Class 3
cancelled
Class 4.1
cancelled
Class 4.2
Cancelled
Class 4.3
Cancelled
Class 5.1
Cancelled
Class 5.2
Cancelled
Class 6.1
Cancelled
Class 6.2
Cancelled
Class 7
Cancelled
Class 8
Cancelled
Class 9
Cancelled
Part III
Cancelled
Hook-Ups And
Cancelled
Connections II
Cancelled
Hook III
Cancelled
Cancelled
Hook-In
Cancelled
Annex to the connection in the
(I).
Standard liquids for the chemical evidence of tolerance
high molecular polyethylene in accordance with point 1551 (6)
For this plastic are used the following standard liquids:
and smáčecího Solution for resource) substances with effect that evokes the
polyethylene strong stress cracks, especially with all of the solutions and products
containing wetting agents.
It's the 1-10% aqueous solution of smáčecího resource. Surface tension
This resource must be at 23rd. (C) 31 to 35 mN/m.
For the purposes of stacking is taken as the basis of the relative density
at least 1.2.
If it is demonstrated sufficient chemical compatibility with smáčecím
means, do not need to test the tolerance of the acetic acid.
b) acetic acid for substances and preparations with the effect of causing the
polyethylene stress cracks, especially for monokarbonové acid and
jednomocné alcohols.
It is acetic acid concentration 98%-100%.
Relative density = 1.05.
Stacking test is taken as the basis of the relative density of not less than 1.1.
For stuffed with goods, which nabobtnává polyethylene more than acetic acid,
but not more than 4%, stuffed with weight, may be sufficient chemical
tolerability demonstrated an storage at 40th. (C) according to the
point 1551 (6) but with the original stuffed with goods.
c) n-butyl acetate/n-saturated solution of butylenacetátem smáčecího resource
for substances and preparations, which nabobtnávají polyethylene up to about 4% and
at the same time show the effect of the release of stress cracks, especially on resources
to protect plants, liquid colors and certain esters.
It is n-butyl acetate concentration from 98 to 100% for storage
score from 1551 point (6).
Stacking test in accordance with section 1555 is used for testing liquid
modified 2% n-butyl acetate with aqueous solution of 1% to 10% smáčecího
resource, in the light of subparagraph (a)).
Stacking test is taken as the basis of the relative density of not less than 1.0.
The filled goods-polyethylene nabobtnává more than n-butyl acetate
to no more than 7.5%, stuffed with weight, may be sufficient chemical
tolerability demonstrated an storage at 40th. (C) in accordance with point
1551 (6) but with the original stuffed with goods.
d) mixture of hydrocarbons (White Spirit) for substances and preparations which
nabobtnávají polyethylene, in particular for hydrocarbons, esters and
ketones.
It is a mixture of hydrocarbons boiling in the range of 160th. (C) to 220
St. C, relative density 0.78-0.80, with a flash point greater than 50
St. (C) and with the content of aromatic hydrocarbons from 16 to 21% (C9 and higher
aromatic hydrocarbons).
Stacking test is taken as the basis of the relative density of not less than 1.0.
The filled goods-polyethylene nabobtnává by more than 7.5%, stuffed
weight, sufficient chemical compatibility may be proved after
as storage at 40th. (C) in accordance with point 1551 (6) but with the
the original stuffed with goods.
e) nitric acid for all substances and preparations which on polyethylene
same or less oxidation, or that lower molecular
weight as a 55% nitric acid.
It is nitric acid at a concentration of at least 55%. For the test
stacking is taken as the basis of the relative density of not less than 1.4.
For goods, which has stronger oxidizing properties than the 55% acid
nitric, or that reduces the molecular weight, must be followed
in accordance with point 1551 (5).
(f)) water for substances which do not attack polyethylene in the manner specified under
a) to (e)), in particular for inorganic acids and lyes, aqueous solutions of salts,
vícemocné alcohols, organic substances in aqueous solution.
Stacking test is taken as the basis of the relative density of not less than 1.2.
II.
The list of substances to which the standard liquids may be assigned according to
point 1551 (6)
CLASS 3
Numbers Indicate the substance Standard liquid
------------------------------------------------------------------
A. substances with a flash point below 23rd. C, non-toxic, non-corrosive
3. b) substances whose vapour pressure at 50th. (C) does not exceed 110
kPa (1.1 bar):
-crude oils from oil and other hydrocarbons
crude oils
-hydrocarbons of hydrocarbons
-substances containing halogenated hydrocarbons
-alcohols, acetic acid
-ethers of hydrocarbons
-aldehydes of hydrocarbons
-ketones of hydrocarbons
-esters of n-butyl acetate in
from growing up to 4
HM.-%, otherwise the mixture
hydrocarbons
4. b) mixture of digits 3b) with point of n-butyl acetate/n-
the boil. the beginning of the boil more butylacetá-tem
than 35th. (C), with a maximum of 55% of the saturated solution
nitrocellulose with a nitrogen content of wetting agent and mixture
not more than 12.6% of hydrocarbons
5 Viscous substances mixture of hydrocarbons
B. Substances having a flash point below 23rd. (C), the venomous
17. b) methanol acetic acid
E. substances having a flash-point between 23rd. (C) to 61st. (C) including
31. c) of a substance with a flash-point of 23
St. (C) to 61st. (C) including:
-kerosene, solventnafta of hydrocarbons
-petrol mixture of hydrocarbons (white spirit White
Spirit)
-hydrocarbons of hydrocarbons
-substances containing halogenated hydrocarbons
-alcohols, acetic acid
-ethers of hydrocarbons
-aldehydes of hydrocarbons
-ketones of hydrocarbons
-esters of n-butyl acetate in
from growing up to 4
HM.-%, otherwise the mixture
hydrocarbons
-substances containing nitrogen mixture of hydrocarbons
34. c) mixtures of substances which digit 31 c) with n-butyl acetate/n-
not more than 55% nitrocellulose with butylacetá-tem
nitrogen content not exceeding 12.6% saturated solution
wetting agent and mixture
hydrocarbons
CLASS 5.1
Numbers Indicate the substance Standard liquid
------------------------------------------------------------------
A. liquid substances supporting combustion (oxidation-acting) and their
aqueous solutions.
1. Hydrogen peroxide and its
solutions of ^ 12)
b) aqueous solutions with a minimum of 20%,
but not more than 60%
hydrogen peroxide-water
c) aqueous solutions with not less than 8%,
but less than 20%
hydrogen peroxide-water
3. a) perchloric acid with more than
50 hm.-% but not exceeding 72 hm.-% nitric acid
pure acid
B. aqueous solutions of solid materials supporting combustion (acting
oxidation).
11. b) Calcium chlorate solution water
potassium chlorate solution water
sodium chlorate solution water
CLASS 5.2
Editor's note. tert.-butylhydroperoxid with more than 40% peroxide, as well as
peroxyoctové acid are excluded from the following digits.
Digit labelling Standard
liquid
------------------------------------------------------------------
1B) all organic peroxides in n-butyl acetate/
technically pure form and in solution has been added with 2%
a solution with the solvent, which with n-butyl acetate
regard to the
3B) their tolerance are in and the mixture of hydrocarbons and
This report covered
the standard liquid "mixture of nitric acid 55%
hydrocarbons "
5B)
7B)
9B)
Ventilation device and seal compatibility with organic peroxides
may be, independently from the construction type of the acid tests
with the help of nitric, demonstrated in laboratory experiments.
CLASS 6.1
Numbers Indicate the substance Standard liquid
------------------------------------------------------------------
B. organic substances with a flash point of 23rd. C or higher or
nezápalné Organics
12. nitrogen-containing Substances with a flash point over 61
St. (C):
b) Anil acetic acid
14. oxygen-containing Substances with a flash point over 61
St. (C):
(c)) ethylenglykolmonobutylether acetic acid
Furfuryl alcohol acetic acid
phenol, acetic acid solution
27. Organic toxic corrosive substances
and the subjects of such substances,
as well as solutions and mixtures
organic toxic corrosive
substances (such as preparations,
preparations and wastes):
(b)) or cresol mixture of cresols, acetic acid
isomers
CLASS 6.2
Numbers Indicate the substance Standard liquid
------------------------------------------------------------------
3 and 4 all other substances to be eligible
cause the disease, which according to the water
650 (5) liquid
CLASS 8
Numbers Indicate the substance Standard liquid
------------------------------------------------------------------
And the acidic nature of the substance.
Inorganic substances
1. b) sulfuric acid water
sulphuric acid, the water used
2. b) nitric acid with not more than 55% nitric acid
acid
4. b) perchloric acid with not more than 50
HM.-% acid, aqueous solution of nitric acid
5. b) hydrochloric acid
(hydrochloric acid) with a maximum
and 36% pure acid, water
(c)), HYDROBROMIC ACID, water
acid jodovodíková water
7. b) with fluórovodíková acid
a maximum of 60% fluórovodíku ^ 14) water
8. b) with tetrafluóroboritá acid
not more than 50% of the net acid water
acid hexafluórokřemičitá water
17. b)
and chromic acid, solution
(c) not more than 30% of the net) acid nitric acid
17. c) phosphoric acid water
Organic substances
32. b) Acrylic acid, acid
formic, acetic acid, acetic acid
mercaptoacetic acid
32. c) acid, methacrylic acid acetic acid
propionic acid
40. c) alkylphenols, liquid acetic acid
(B) the substance is alkaline in nature.
Inorganic substances
42. (b)) sodium hydroxide solution water
and (c)) potassium hydroxide, water
43. c) ammonia (ammonia), an aqueous solution of water
44. b) hydrazine, aqueous solution with
not more than 64% hydrazine hm.-water
C. Other corrosive substances
61. chloritanů and nitric acid solutions
chlornanů ^ 13)
63. c) formaldehyde solution, water
Hook-VI
Cancelled
Hook-VII
Cancelled
Hook-Ups VIII
Cancelled
The list of numbers to indicate the danger
1801
(1) the number to indicate the hazards for substances of classes 2 to 9 consists of two
or of three digits.
Numbers refer generally to these dangers:
2 a gas leak or pressure or chemical reaction
3 Flammability of liquids (par) and gases or liquid substance capable of
samoohřevu
4 Flammability of substances in the solid state or hard substance capable of samoohřevu
5 Oxidizing (burning-capable) effect
6 Toxicity or risk of infection
7 Radioactivity
8 Corrosion
9 the risk of spontaneous violent reaction
Editor's note.
Spontaneous backlash within the meaning of the digits 9 includes substances of
stemming the possibility of explosion hazard, dangerous rozpadovou or
polymerization reaction, whereby a significant heat or soot ignition
and/or toxic gas.
Doubling of the digit indicates the increase in the relevant risk.
If he can be a danger of the substance as indicated by single-digit enough, make up
the digit in the second place by 0.
This combination of numbers, however, have a special meaning: 22, 323, 333, 362,
382, 423, 44, 446, 462, 482, 539, 606, 623, 642, 823, 842 and 90 [see
paragraph (2)].
If it is before the number to indicate the danger of the letter "X", it means
the substance reacts dangerously with water. Such substances may be water
used only with the consent of an expert.
For substances and articles of class 1, instead of a number to indicate the danger
uses the classification code in accordance with section 100 (4). Classification code consists
from:
-the numbers of the subclass as specified in point 100 (6), and
-the compatibility group letter in accordance with section 100 (7).
(2) the numbers to indicate the danger referred to in section 1802 have the following meaning:
20 inert gas
22 deeply refrigerated gas
223 deeply refrigerated flammable gas,
225 deeply refrigerated, oxidizing (burning support)
gas
23 flammable gas
239 flammable gas, which can spontaneously lead to violent
response
25 oxidizing (burning support) gas
26 toxic gas
263 toxic gas, flammable
265 toxic, oxidizing (burning support) gas
268 toxic, corrosive gas
30-flammable liquid substance (flash-point between 23rd. (C) to
61st. (C) inclusive), or
-a liquid substance or solid in
molten state with a flashpoint over the 61st. (C),
heated to or through their flash-point, or
-a liquid substance capable of samoohřevu
323 flammable liquid substance that reacts with water and forms a
flammable gases
X323 combustible liquid substance, which dangerously with water
reacts and forms a flammable gases)
33 lightly incendiary liquid substance (flash point below the
23rd. (C))
333 pyroforní liquid substance
9033 pyroforní liquid substance, which dangerously with water
responds *)
336 lightly incendiary liquid substance, toxic
338 lightly incendiary liquid substance, corrosive
X338 lightly flammable liquid substance, corrosive, that with water
reacts *)
339 lightly incendiary liquid substance, which may lead to
spontaneous violent reaction
36 flammable liquid (flash-point between 23rd. (C) to
61st. (C) inclusive), slightly toxic or liquid substance
capable of samoohřevu, Ivy
362 flammable liquid substance, toxic, which reacts with the
water and develops a burnt gases
X362 combustible liquid substance, toxic, water
reacts and evolving flammable gases)
368 flammable liquid substance, toxic, corrosive
38 flammable liquid (flash-point between 23rd. (C) to
61st. (C) inclusive), slightly corrosive or substance capable of
samoohřevu, liquid, corrosive
382 flammable liquid substance, corrosive, which reacts with water
and evolving flammable gases
X382 flammable liquid substance, corrosive, that with water
reacts and evolving flammable gases)
39 flammable liquid substance, which can spontaneously lead
the sharp reaction;
40 flammable solid or substance capable of samoohřevu
or spontaneously decomposing the substance
423 solid which reacts with water, and develops the incendiary
gases
X423 ignition solid that dangerously with water
responds and evolves flammable gases)
43 pyrophoric (pyroforní) solid
44 flammable solid, which at elevated temperature
located in molten state
446 flammable solid, toxic, which increased
the temperature is in the molten state
46 flammable substance or substance capable of samoohřevu, solid,
Ivy;
462 toxic solid which reacts with water, and
evolving flammable gases
X462 solid which reacts dangerously with water *) and
develops toxic gases
48 flammable substance or substance capable of samoohřevu, solid,
corrosive
482 corrosive solid which reacts with water, and develops
flammable gases
X482 solid which reacts dangerously with water *) and
develops the corrosive gases
50 oxidizing (burning support) the substance
539 flammable organic peroxide
55 strongly oxidizing (burning support) the substance
556 strongly oxidizing (burning promoting) substance, toxic
558 strongly oxidizing (burning promoting) substance, corrosive
559 strongly oxidizing (burning support) a substance that
can lead to spontaneous reaction
56 oxidizing (burning promoting) substance, toxic
568 oxidizing (burning promoting) substance, toxic,
corrosive
58 oxidizing (burning promoting) substance, corrosive
59 oxidizing (burning support) which can
lead spontaneously to the reaction
60 toxic or slightly toxic substance
606 substance eligible trigger contagion
623 toxic liquid substance that reacts with water and
evolving flammable gases
63 toxic substance, flammable (flash-point between 23rd. (C) to
61st. (C) including)
638 toxic substance, flammable (flash-point between 23rd. (C) to
61st. (C) inclusive), corrosive
639 toxic substance, flammable (flash-point between 23rd. (C) to
61st. C inclusive), which can spontaneously lead to violent
response
64 toxic solid, flammable or capable of
samoohřevu
642 toxic solid which reacts with water, and develops
flammable gases
65 toxic substance, oxidizing (burning support)
66 highly toxic substance
663 highly toxic substance, flammable (flash-point not more than
61st. (C))
664 highly toxic solid, flammable or capable of
samoohřevu
665 highly toxic substance, oxidizing (burning support)
668 highly toxic substance, corrosive
669 highly toxic substance, which can spontaneously lead
to violent reaction
68 toxic substance, corrosive
69 toxic or slightly toxic substance, which can lead
spontaneously to the violent reaction
70 radioactive substance
72 radioactive gas
723 radioactive gas, flammable
73 radioactive liquid substance, flammable (flash-point
a maximum of 61st. (C))
74 radioactive solid, flammable
75 radioactive substance, oxidizing (burning support)
76 radioactive substance, toxic
78 radioactive substance, corrosive
80 corrosive or slightly corrosive substance
X 80 corrosive or slightly corrosive substance with water
reacts *)
823 corrosive liquid substance that reacts with water and develops
flammable gases
83 corrosive or slightly corrosive substance, flammable (point
an outbreak of 23rd. (C) to 61st. (C) including)
X 83 corrosive or slightly corrosive substance, flammable (point
an outbreak of 23rd. (C) to 61st. (C) including) which
reacts with water *)
839 corrosive or slightly corrosive substance, flammable (point
an outbreak of 23rd. (C) to 61st. (C) including) that can
lead spontaneously to the reaction
X839 corrosive or slightly corrosive substance, flammable (point
an outbreak of 23rd. (C) to 61st. (C)), which may lead
spontaneously to the violent reaction and which reacts dangerously
with water *)
84 corrosive solid, flammable or capable of samoohřevu
842 corrosive solid which reacts with water, and develops
flammable gases
85 corrosive or slightly corrosive substance, oxidizing (burning
support)
856 corrosive or slightly corrosive substance, oxidizing (burning
supporting) and Ivy
86 corrosive or slightly corrosive substance, toxic;
88 highly corrosive substance
X88 strongly corrosive substance that dangerously with water
responds *)
883 highly corrosive substance, flammable (flash-point from
23rd. (C) to 61st. (C) including)
884 highly corrosive solid, flammable or capable of
samoohřevu
885 highly corrosive substance, oxidizing (burning support)
886 highly corrosive substance, toxic
X886 strongly corrosive, poisonous, that with water
reacts *)
89 corrosive or slightly corrosive substance, which can lead
spontaneously to the violent reaction
90 environmentally hazardous substance
various dangerous substances
99 miscellaneous dangerous substance in the zahřátém State
(3) to indicate the Number referred to in paragraph (2) are listed in the
of dangerous goods (RID/PNZ) (I, II, and III) point 1802.
List of dangerous goods (RID/PNZ)
1802
The lists are composed of seven columns:
and the number to indicate the substance
This column lists the numbers to indicate the substance of the listing of substances
different classes. These numbers to indicate the substance was taken from the Recommendations
The United Nations transport of dangerous goods.
(b) the substance or object naming
In this column are listed:
-all naming of substances and articles, as well as all the naming
designation of the N.E.C., that are in the list of substances of the classes of
printed in italic,
– substances and articles which, pursuant to the provisions of RID/PNZ is not specifically
be transported,
-substances and articles which are not subject to the provisions of RID, namely/PNZ.
The naming of lists as they are prescribed to write to
the Bill of lading. Then there are the listed synonyms, with reference to the main
naming.
The lists are not descriptions of mixtures, preparations, etc., which are not in
RID/PNZ listed in italics, because these descriptions may not be used as a
description of the goods in the consignment note. For the classification of mixtures and
products, see section 3 (3), as well as the listing of substances the individual classes.
Substances of RID/PNZ, which is permitted in the boiler,
battery wagons, wagons with removable reservoirs, nádržkových
containers, eg. in the bulk State are printed in bold.
(c) class, numbers, and, where appropriate, group
This column lists the class numbers, and, where appropriate, group of RID/PNZ,
However, with the following particularities:
-for substances and articles of class 1: the classification code and numbers,
-for substances and articles of class 7: the class and sheet,
-for substances and articles, namely not allowed under the terms of
RID/PNZ transported: the reference to "disabled",
-for substances and articles which are not subject to the conditions of RID/namely the PNZ:
the "free" link.
(d) the number to indicate the danger
-This column contains the number of the indications of danger in accordance with section 1801
(2).
e. Sticker to indicate danger
This column lists the patterns of the labels to indicate the danger that
must be placed.
If they are for boiler cars and cistern containers prescribed additional
stickers to indicate danger, then the numbers are these stickers appear in
brackets.
If for certain types of organic peroxides listed sticker the model 8
parentheses, not the subsidiary label prescribed for all organic
peroxides of this type (see the provisions of point 551).
For radioactive material (class 7) However, in this column, point given in the
which are the conditions of bonding. On these issues, care must be taken to
compliance with paragraphs 8 and 9.
f. number of NHM (Nomenclature Harmonisée Marchandises-Harmonised
nomenclature of goods)
In this column indicates the position of the goods according to NHM-Harmonised
the nomenclature of goods for transport (annex 3 to the
UIC-221). Because dangerous goods assigned according to NHM-bays
the policy that is from RID/PNZ marshaling different, is not always possible,
for one substance of RID/PNZ allocate one NHM-position.
This applies especially to the summary description and designation of the N.E.C. in these
cases, you can determine the correct position of the NHM-only if it is
known chemical or technical name of the goods. If it is possible
to specify the correct position of the NHM-incomplete, are instead of missing numbers
shows the asterisk (*).
The data in this column are not legally binding.
Endnote references:
*) depends on the latter-laden goods
**), NHM-the position of the various according to the contents of the container
NHM-various positions) by type of goods
A. alphabetical list
In this alphabetical list of substances and articles are listed for each
classes of RID/PNZ according to the explanatory notes to the column "Name of the substance or
the subject ".
If the substance or object is not mentioned, it is to be checked,
whether the substance or object
-not be transported under the provisions of the exclusive class [see
section 1 (3)], or
-You can assign a general indication or designation n.e.c. some class,
or
-is allowed to be transported under the provisions of some of the free class without
special conditions [see section 1 (4)].
The names of substances and articles are listed in alphabetical order. In doing so, they are not
taken into account, and preceded by Arabic numerals or as a prefix o-, m-, p-,
n-, sec-, tert.-, N-, Alpha-, beta-, omega, etc.
-----------------------------------------------------------------
*) Water may be used only with the consent of an expert.
Class and number ČísloNálepka Number
The naming of the substance or article numbers to kk NHM
where appropriate, the indication of označeníoznačení
Group risk látkynebezpečí
pattern No.
-------------------------------------------------------------------------------------------------
(a) (b) (c) (d) (e) (f)
-------------------------------------------------------------------------------------------------
Abietát (resinát) aluminium 4.1 12 c 40 2715 4.1 380620
Abietát (resinát) cobalt, 4.1 12 c 40 1318 4.1 380620
break
Abietát (resinát) manganese 4.1 12 c 40 1330 4.1 380620
Abietát (resinát) calcium 4.1 12 c 40 1313 4.1 380620
Abietát (resinát) calcium 4.1 12 c 40 1314 4.1 380620
melted and stiff
Abietát (resinát) zinc 4.1 12 c 40 2714 4.1 380620
Acetal (1.1-Give) 3 3b 33 1088 3 291100
Acetaldehyde (Ethanal) 3 1a 33 1089 3 291212
Acetaldehydoxim 3 31 c 30 2332 3 292990
Acetic anhydride (anhydride 8 32b) 2 83 1715 8 + 3 291524
acetic)
Acetoarzenitan copper 6.1 51b 60 1585 6.1 284290
Acetoin: see
Acetylmethylkarbinol
Acetone 3 3b 33 1090 3 291411
Acetonitrile (Methylkyanid) 3 3b 33 1648 3 292690
Acetone cyanohydrin, stabilized 6.1 12a 669 1541 6.1 292690
Acetylacetone: see 2.4-
Pentandion
Acetylacetonperoxid as a paste,
= 32% see 52-
80%: see organic peroxide
type C, liquid
2.2-Di-(tert.-Butyl-peroxy)-propane, = < 42%:
see organic peroxide type D,
hard
2.2-Di-(tert.-Butyl-peroxy)-propane, = < 52%:
see organic peroxide type D,
liquid
Butylacetáty 3 31 c 30 1123 3 291590
Butylacetáty 3 .3B 33 1123 3 291590
Butylakryláty, stabilized 3 31 c 39 2348 3 291612
Butylalkoholy (Butanoly) 3 31 c 30 1120 3 290514
Butylalkoholy (Butanoly) 3 3b 33 1120 3 290514
di-n-butyl amine 8 54b 83 2248 8 + 3 292119
n-butyl amine 3 22b 338 1125 3 + 8 292119
2-(di-n-Butylamino)-ethanol 6.1 12 c 60 2873 6.1 292219
Butylbenzeny 3 31 c 30 2709 3 290290
Butylbenzylphthalate: see substance
threatening the environment,
liquid, n.o.s.
n-Butylbromid (1-Brombutan) 3 3b 33 1126 3 290330
SEK. Butylbromid: see 2-Brombutan
1.2-Butylenoxid, stabilized 3 3b 339 3022 3 291090
di-n-Butylether (Dibutylether) 3 31 c 30 1149 3 290919
n-3b 33 1128 3 291513 3 Butylformiát
Butylfosfát (mono-n-8 38 c 80 1718 8 291900
Butylfosfát)
di-n-Butylftalát: see substance
threatening the environment,
liquid, n.o.s.
tert.-Butylhydroperoxid + Di-tert.-
butylperoxid = < 82% + > = 9%:
see organic peroxide type C,
liquid
tert.-Butylhydroperoxid, > 79-90%:
see organic peroxide type C,
liquid
tert.-Butylhydroperoxid, = 79% see 42-100%:
see organic peroxide type D,
liquid
tert.-Butylkumylperoxid, = 42% see 52-
100%: see organic peroxide
Type B, hard
tert.-Butylmonoperoxymaleat, = < 52%:
see organic peroxide type C,
liquid
tert.-Butylmonoperoxymaleat, = < 52%:
see organic peroxide type E,
hard
Butylnitrity 3 31 c 30 2351 3 292090
Butylnitrity 3 .3B 33 2351 3 292090
Di-tert-Butylperoxid, = < 32%: see organic peroxide type F, liquid Di-tert.-Butylperoxid, > 32-100%: see
organic peroxide type E,
liquid
1.1-Di-(tert-Butylperoxy.) cyclohexane, > 80-
100%: see organic peroxide
Type B, liquid
1.1-Di-(tert-Butylperoxy.)-3,5,7, 5-
trimethylcyklohexan = < 32%: see organic peroxide type E, liquid 1.1-Di-(tert-Butylperoxy.)-3,5,7, 5-trimethylcyklohexan, > 57-90%:
see organic peroxide type C,
liquid
1.1-Di-(tert-Butylperoxy.)-3,5,7, 5-
trimethylcyklohexan = < 57%:
see organic peroxide type D,
hard
1.1-Di-(tert-Butylperoxy.)-3,5,7, 5-
trimethylcyklohexan = < 57%: see organic peroxide type E, liquid 1.1-Di-(tert-Butylperoxy.)-3,5,7, 5-trimethylcyklohexan, > 90-
100%: see organic peroxide
Type B, liquid
1.1-Di-(tert-Butylperoxy.)-cyclohexane,
= 13% see 52-77%
see organic peroxide type D,
liquid
tert.-Butylperoxybenzoat, = < 52%: see organic peroxide type D, solid tert.-Butylperoxybenzoat, > 77-100%:
see organic peroxide type C,
liquid
tert.-Butylperoxybutylfumarát,
= 52% see 77-94%:
see organic peroxide type B,
hard
Benzoyl peroxide, =: see < 77%
organic peroxide type C, solid
Dibenzyldichlorsilan 8 X 80 2434 8 293100 36b
Diboran, compressed 2 1TF 263 1911 6.1 + 3 285000
1.2-dibromo-3-chloropropane: see
Pesticide-a chemical compound
chlorine
33 c 90 1941 9 290347 9 Dibromdifluormethan
1.2-dibromoethane (Ethylendibromid) 6.1 15a 66 1605 6.1 290330
6.1 Dibromchlorpropany 6.1 15 c 60 2872 290349
Dibrommethan 6.1 15 c 60 2664 6.1 290330
Dibutylether (di-n-Butylether) 3 31 c 30 1149 3 290919
Dicrotophos: see Pesticide-
an organic compound of the phosphorus
Dicumarol: see Pesticide-
a derivative of coumarin
Dicyklohexylamin 8 53 c 80 2565 8 292130
Dicyklohexylamoniumnitrit 4.1 11 c 40 2687 4.1 292130
Dicyclopentadiene 3 31 c 30 2048 3 290219
Dieldrin: see Pesticide-
the organic compound of chlorine
Diethoxydimethylsilan 3 .3B 33 2380 3 293100
1.1-Give (Acetal) 3 3b 33 1088 3 291100
1.2-Give: see
Ethylenglykoldiethylether
Diethoxymethan 3 .3B 33 2373 3 290919
3.3-Diethoxypropen 3 .3B 33 2374 3 291100
Diethylamine 3 22b 338 1154 3 + 8 292112
3-(Diethylamino)-propylamin 3 33 c 38 2684 3 + 8 292129
2-8 83 2686 Diethylaminoethanol 54b 8 + 3 292219
N, N-Diethylanilín 6.1 12 c 60 2432 6.1 292142
Diethylbenzeny (o-, m-, p-) 3 30 2049 3 290290 31 c
Diethyldichlorsilan 8 37b X 83 1767 293100 8 + 3
Diethylenglykoldinitrát, 1.1 (D) 4 1.1 D 0075 1 + 15 360200
znecitlivěný
Diethylenetriamine [bis-(2-Amino-8 53b 80 2079 8 292129
ethyl)-amine]
Diethyl ether (ethyl ether) 3 2a 33 1155 3 290911
N, N-Diethylethylendiamin 8 83 2685 54b 8 + 3 292129
Diethylkarbonát 3 31 c 30 2366 3 292090
Diethylketon 3 .3B 33 1156 3 291419
Diethylsulfát 6.1 14b 60 1594 6.1 292090
Diethylsulfid 3 .3B 33 2375 3 293090
Diethylthiofosforylchlorid 8 35b) 1 80 2751 8 292010
Diethylzinek 4.2 31a 9033 1366 4.2 + 4.3 293100
Difenacum: see Pesticide-
a derivative of coumarin
Diphenyl: see contaminating
the environment, solid, n.o.s.
Difenylaminochlorarzin 6.1 34a 66 1698 6.1 293490
Diphenyl ethers: see substance
threatening the environment,
solid, n.o.s.
Difenylchlorarzin 6.1 34a 60 1699 6.1 293100
Difenylmagnesium 4.2 31a 9033 2005 4.2 + 4.3 293100
Difenyloxid-4.4-
disulfonohydrazid [p, p '-oxybis
(benzensulfo-hydrazides)]: see
a substance will
lying, type D, solid
Difenzoquat: see pesticide, n.e.c.
Difluordibrommethan: see
Dibromdifluormethan
1.1-Difluorethan (gas like 2 2F 23 1030 3 (+ 1) 290330
refrigerant R 152a)
1.1-Difluorethylen (gas as
refrigerant R 1132a) 2 2F 239 1959 3 (+ 1) 290330
Difluormethan (gas like 2 2F 23 3252 3 (+ 1) 290330
refrigerant R 32)
Dihydrid titanium 4.1 14b 40 1871 4.1 285000
Dihydrid zirconium 4.1 14b 40 1437 4.1 285000
Dihydrogenfosfid leaded 4.1 11b 40 2989 4.1 283510
Lead Dihydrogenfosfid 4.1 11 c 40 2989 4.1 283510
2.2-Dihydroperoxypropan, = < 27%:
see organic peroxide type B,
hard
2.3-Dihydropyran 3 3b 33 2376 3 290920
1.4-Dihydroxybenzen: see
Hydroquinone
Dichlofenthion: see Pesticide-
an organic compound of the phosphorus
1.1-Dichloro-1-nitroethane 6.1 17b 60 2650 6.1 290490
1.3-Dichloro-2-propanol 6.1 17b 60 2750 6.1 290550
Dichloracetylchlorid 8 35b) 1 X 80 1765 8 291590
Dichloranilíny 6.1 12b 60 1590 6.1 292142
o-Dichlorobenzene (1.2-6.1 15 c 60 1591 6.1 290361
Dichlorobenzene)
1.2-Dichlorobenzene (o-Dichlorobenzene) 6.1 15 c 60 1591 6.1 290361
p-Dichlorobenzene: see substance
threatening the environment,
solid, n.o.s.
Di-(2-Dichlorbenzoylperoxid as
Paste with silicone oil
= 52% see